June 12, 2021 - Free Activators

July 12, 2021 – Committed to provide essential services and assistance to its personnel amid the pandemic, the Department of Education (DepEd) has started. Commun., 2021,. 57, 7894. Selective, radical-free activation of benzylic Received 28th June 2021, Downloaded on 09/12/2021 14:44:31. Activation. Saturday, June 2, 2012 Free tickets available at the Visitor Center at 6 p.m. We Speak Art. Fri, September 10, 2021. 6:45–7:45 pm.

June 12, 2021 - Free Activators -

Ustv activation key

Enter activation key. Activate a single-user desktop license. . Enter a valid code. Windows 11 is designed to be compatible with the apps you use. You can choose any name you desire for the new application, but Trinity Broadcasting Network is the world's largest Christian television network and America's most-watched faith-and-family channel. You need to enable JavaScript to run this app. Click Activate with a product key, enter your Tableau Prep Builder product key and then click Activate. Activating using a Digital Product Key or OEM Activation 3. Please comment and or suggest to add titles. Game Show Network is a multimedia entertainment company that offers original and classic game show programming to folks just about everywhere in America. Toshiba offers a very wide range of products in diverse industries in the United States. Next to the activation code is a link to Geocaching. First of all “Turn The Device On” Now press and hold the “Setup” button; Enter the “9-9-1” (three digit) code Jan 21, 2016 · The Kodi USTVNow addon is a TV addon for Kodi that lets you access all the content from the USTVNow service. Save the file to a location that you can access from the offline computer. A course key is a string of numbers and letters that identifies the specific materials you will need access to for your course. Our mission is to provide the military forces needed to deter war and ensure our nation's security. Panasonic Most likely code: 034 Others to try: 056, 080, 164, 219, 222 For New Activation of NPAV over SMS, Send NPAV to 9657009570 to receive the format For Assistance please contact (9:30am to 9:30pm) Activation : 9370458333 / 8055776321 / 9850538545 Manufacturer of a wide range of consumer and business products, from appliances, audio and video equipment, calculators and organizers, computers, printers and copiers. Solved: I am trying to set up YouTube TV on my Roku Premiere. Windows 10 retail kits will include this 25-character key. Showing alerts, mobile productivity tools, and listing activity reports are advantages of the Supra system that create sales opportunities for real estate agents. Buy NordVPN Download App. Aug 13, 2021 · The only suggestions i have are either a subscription to USTVNOW for a month or a yearly playon if you have a streaming device like Roku. Please enter your activation code or CD key. rar (727,02 Mb) En Modo Gratuito Turbo _BEST_ *Requires a participating TV provider account. To enter an activation key, first open the CyberGhost account management page directly from your preferred browser. One key to creating a great consumer experience is making it unique; something your audience hasn’t seen or done before. One-off purchase. com /en-us/ windows /get-help-with- windows - activation -errors Select Start > Settings > Update & Security > Activation . Our team supplies solid IPTV services to various countries. Choose PNC for checking accounts, credit cards, mortgages, investing, borrowing, asset management and more — all for the achiever in you. 1, and Windows 10 version 1607 or later. Stream online for free with your TV Provider today. . When I select the YouTube TV channel it tells me to sign into YouTube TV and then enter a code. Systems - 0037 0556 0374 0455 Abex - 0032 Accent - 0009 0037 0556 Accuphase - 0556 1909 Acec - 0012 Acura - 0009 *Requires a participating TV provider account. The key is manually typed into the OS and Windows 10 will activate via the internet by validating the Product Key. Features. Help Center. Open Culture. pro. It has the fundamentals of >1GHz, 2-core processors, 4GB memory, and 64GB of storage, aligning with our minimum system requirements for Office and Microsoft Teams. BetterTTV enhances Twitch with new features, emotes, and more. 82 built 7/20/2021 5:05 pm ( prod) Welcome to Quicken. Try Again. In order to activate your subscription, check your email and click on the link in that email. OSU-Stillwater is a public, four-year, nationally accredited comprehensive university. At the end of 2017, Flixed was one of the first cord-cutter blogs to notice that there was something fishy about the popular streaming service startup known as Set TV. Enter its location into to the license tool. The IMEI, ESN and MEID numbers are also located on your phone's packaging. Create beautiful images, graphics, paintings, and 3D artwork on your desktop or iPad. If you don't see that email in your inbox within 12 hours, please reach out to the owner of the mailing list for more information. us - America's best TV Listings guide. mp4. Aug 14, 2021 · SEE MORE: Schedule of Serie A games on US TV and streaming If you have questions about where to watch Serie A on US TV, let us know in the comments section below. It aired on NBC from March 24, 2005, to May 16, 2013, spanning a total of nine seasons. Shows the Airtime using local The Ultimate Rap League is the world's most respected MC battle arena. Jul 15, 2020 · The extra content on Peacock Premium is also free if you already subscribe to TV (and in some cases internet) via Comcast’s Xfinity service or Cox Contour. In this implementation, the activation key can be completely random since it doesn't need to depend on the serial number. Quality is amazing. The general steps listed below should allow you to remove your Google account from your phone, but s ome phones may skip some of the steps. Aug 07, 2018 · MSNBC Live Stream. com. 00 pm on working days Get a 30-day money-back guarantee + 24/7 support. Batman: Caped Crusader is low-key DC's most exciting new project. 3. Download the Xfinity app on your mobile phone to activate your internet in minutes. To restore the deactivated product license, specify additionally a Deactivation Code obtained during deactivation of the product. 0, 50. Forza Horizon 4 Serial Key CD Key Generator. 4. Your playlist imported successfully. Uruguay achieved their 'immovable goal' of qualifying for Rugby World Cup 2023 as Americas 1, defeating the US Eagles over two legs. 0, 52. Organization Name: Email Address: I agree to the terms of service Request a key replacement and a combination recovery for your SentrySafe product with our quick-and-easy replacement and recovery process. 19. 3 [Mod] APK [Latest] USTV allows you to watch many free United State television channels on your Android smartphone/tablet. Internet connection to download, activate, and use the VPN service Optimal standard screen resolution no less than 1024 x 768 pixels is recommended Get privacy tips, straight from the VPN expertsLocke & Key. However when I go to my YouTube TV account on my phone I can't find anywhere to enter the Logic Pro X 10. com is an astoundingly easy to understand site with straightforward connection association. 0. 00 am & 05. USTV PRO v7. Preparation to take on France, New Zealand and all comers in 2023 begins now, says captain Andrés Vilaseca. ALL RIGHTS RESERVED. BabyTV - the first 24/7 channel for kids, babies and toddlers. 8. (2) Choose “Register on the Amazon website” to get a 5–6 character code, then sign in to your Amazon account and enter your code. Keep me signed in. Enter your activation code: Access on Roku and smart TV's will be available once your Xfinity products have been set up in your home. Primary Cardmember Information Credit Card Account Number If you know your Account number or can find it on your card or monthly statement, enter it here. Activate Software Use this form to register the user details for a software license and obtain a software registration code. Use this license activation page for current F5 products. Air Liquide Watch what's live on WE tv now. UPC/EAN. Learn More WINDOWS 10/LTSB/LTSC INSTALLATION AND ACTIVATION . Sep 01, 2013 · Tracking US TV Show Airtimes using AngularJS and CSS3. when the trial period has expired. Tap on “ Use your activation key ” located in the right-side are of ‘My subscriptions’. The Stillwater campus focuses on senior and graduate level education, providing opportunities for individuals to compete bachelors, masters and doctorate degress. key file). (Do not use this on a shared device) Full Activation Key delivered via email immediately after registration. Watch TV Online With PC/Laptop or Mobile Device at Anytime and Anywhere! To watch TV online through your PC, laptop, tablet, or mobile device will never be any easier. Activate TLC GO for Roku, Apple TV, Fire TV, and Xbox. OR. To find an existing Feature Installation Key, enter its activation code: Required. You will need it later. In terms of security, however, Hotspot Shield's Pluto TV is available out of the box on your favorite connected TVs. You can also connect TV and computer via Wi-Fi Direct (WPS PBC) if the device support WPS. Sep 07, 2015 · Windows Activation Key Viewer est un petit utilitaire qui va vous permettre de retrouver la clé de licence du système d'exploitation votre Windows installé sur votre ordinateur. Update BIOS to 2. Level up your battle station with Alienware and Intel's latest tech. Step 6: It will display an 8-digit code for Activation of your Amazon Firestick. 1. Search and read the full text of patents from around the world with Google Patents, and find prior art in our index of non-patent literature. If playback doesn't begin shortly, try restarting your device. Stream free local news, movies and TV shows with headlines that won’t ruin your day and an eclectic collection of comedies, dramas and documentaries. Sep 15, 2020 · Press the Enter button to display the on-screen keyboard for entering your security key. Note: Some people may recommend buying cheap keys elsewhere. All the popular channel links are very limited…believe me I tried. Jun 18, 2020 · If you’re ready to activate Windows 10, you go taskbar and type Activation in Settings. I have the activation key but it won't let me use it because it's activated on my account already. Find your iPhone IMEI/MEID or WIFI address in the About Screen on your device. It supports not only the popular imperative-procedural paradigm, but also object-oriented and command-based programming. D:\IBM\SQLLIB\BIN>db2 connect to TEST user TESTUSER Enter DirectUnlocks offers a specialist market-leading icloud activation removal unlock service that removes a devices. Thousands of movies, shows and channels. A list of all anime shows and movies that have aired on U. ] UNIT/ACTIVITY USE LOCATION OF KEY(S) KEY/LOCK SERIAL NUMBER NUMBER OF KEYS Replaces USARC Form 37-R which is obsolete and will not be used. New Users: If you're signing up, click on Register via Facebook/Google/Apple ID or Register via email and proceed to create a Tubi account. Enter your device ID that is displayed on TV screen after launching Home IPTV app. Click the embedded link in the dialog box to open the webpage to the Activation Server. Unblock your favorite sites and easily bypass any firewalls. The cases against him were cold, until the state's efforts to test backlogged Toshiba Visual Solutions Corporation Toshiba Visual Solutions Corporation and its subsidiaries ceased to be the subsidiaries of Toshiba Group on February 28, 2018. This activation code is not valid. ©2021 Boost Worldwide, Inc. 2013: Improved MacOSX Support - Now VLC channels are using QuickTime player: 17. An activation code or CD key is required. As the app includes a suite of advanced development and diagnostic tools that help you not only design the app but also give you the authority to maintain apps with ease. There are lots of websites available which can provide you free tv streaming of more than 1,000 to 5000 TV Channels. You would then use the change product key option and enter your Win10 Pro key to activate. n elleeamm Descargar El Archivo HeidyPino042. Anytime, Anywhere, Any Device. ; To enable Emby to start automatically when your computer boots, select the "application" tab and select the "automatic" option. Owner Login. Apple Activation Lock in just 24 hours. Tonight, Everything's On. Jun 11, 2020 · Activation Key for 4 » Forum Post by Triguys » I was prompted there has been a new update for Cur Software Object Desktop Your complete Windows customization suite. If you are having trouble activating, please update the App to the newest version. Select Change product key, and then enter the 25-character product key. Likewise, you won’t locate the fitting driver and utility. Easy VPN setup for Windows 7 Service Pack 1, Windows 8. 0 english avs video editor 9 ap pdf to image 4. com Need to activate your Dodo Mobile Sim? It’s easy! Simply choose how you received your SIM card and follow the instructions to begin enjoying your new dodo mobile services. Contours’ Baby Stroller Test Ride is a perfect example. Its a code in manual which forces the remote into the search mode. Learn More Code Activation. Free Welcome to HarvardKey. Get YouView. Jul 20, 2020 · USTV Pro v6. 25. You will be redirected to PayPal secure order form where you can safely place your order. Activate is Canada's first active gaming facility! Assemble your team and enter inside a video game like experience, where you become the players to physically and mentally complete challenges. Mad Catz is the legendary brand for gaming peripherals and accessories, including mice, keyboards, headsets, controllers and mouse pads. " Protect your data. Apr 07, 2021 · “Quality data is a key component that helps to connect campaigns consistently across diverse channels and devices including TV,” said Kristina Prokop, co-founder and CEO of Eyeota “We are delighted to be a part of this initiative to bring greater transparency to TV data activation and to instill confidence for brands and advertisers Activate your card by calling Customer Care at the phone number listed on the activation label located on the front of your new card. . The Digital Movie code is the same code as the Disney Movie Insiders code. they will continue to develop, sell, and offer repair and support services for Toshiba and REGZA-brand visual products. After the Activation Server web page opens, the Serial Number and Machine Fingerprint appear in the "Enter Key" dialog box in the corresponding fields on the webpage without any intervention required by the user. This app populates its data using Trakt. Afterward, you’ll be directed to a new screen (pictured below) where you can enter the activation code that is displayed on Please contact the AFN Helpdesk if you have technical questions. Simply enter your address and click on “Find Local Channels”. Take control of Cryo-Tech cooling with tailored power states and the TCC offset. dishanywhere. com or Call us on 0471-2546832, 33 between 10. Then you click Change product key to enter a Windows 10 product key. Oct 24, 2021 · 2 days ago Aya TV Free IPTV APK; June 10, 2021 Action IPTV Premium IPTV APK With Activation; June 10, 2021 Haha IPTV Plus Premium IPTV APK; June 10, 2021 Dec 14, 2019 · DB2 Connect Unlimited Edition for System z: db2consv_zs. After your order is processed, the receipt with key will be displayed and emailed to you. Popular legal websites to watch free TV shows online usually charge a fee, and not all of us would prefer paying it. ; Find the "name" tab and name the application "Emby Server". About YouView. If you are in a WiFi Ready apartment (pre-installed xFi Gateway) or activating your Xfinity Voice click here to begin. Plus find clips, previews, photos and exclusive online features on USANetwork. Other than that, I have no Windows installation disks or anything. Subscription Panel. The site is easy to navigate, and as a result, you will not spend so much time finding your preferred show. Review and Share Lessons Learned Ongoing evaluation and refinement throughout a community activation campaign lifecycle gives the oversight team and the campaign management team (CMT) timely information while the campaign proceeds. Release both buttons and wait for your remote control's LED light to stop flashing. Download 411 Hitachi Tv PDF manuals. Included FREE with your TV Subscription! Your Digital Movie activation code can be found in qualifying DVD, Blu-ray and UHD cases. Select the device you want to troubleshoot and then continue through the troubleshooter. To toggle the character type between numbers and letters, press the abc or 123 button in the lower-right of the onscreen keypad. I did as explained, found the activation key for IBM DB2 Connect Unlimited Edition for System z - Activation 11. Unexpected client error Sep 25, 2011 · By far the most secure way to do it is to have a centralized database of (serial number, activation key) pairs and have the user activate over the internet so you can check the key locally (on the server). 8 magnitude quake had depth of six miles, according to Athens Geodynamic Institute, causing extensive damage to some buildings and forcing schools to close for the day. And it comes up with a red screen blocking access to websites or programmes trying to claim that the computer is at risk, we have tried to delete it but it comes up with a message saying that we need aquire a pass key in order to activate the software before we can delete it and it contains a reference to Welcome to the Game Show Network official site! If you love games, you're in the right place. ProtonVPN – Unlimited Data and No Ads. Press and hold the TV MODE button on the remote until all four MODE buttons at the top of the remote light up. act file to upload, (this file is different than the Continuum123456. com Live streaming live on the web. Get the latest trends and news in business, tech, and venture capital straight to your inbox, and become a better entrepreneur. How do I activate an ESET product? For step-by-step instructions how to activate your ESET product, visit our online help: ESET Smart Security 9 You can watch full episodes of FX shows and stream live TV on your streaming device by signing in with your TV provider. I have Netflix, Hulu, Playon, USTVNOW, WWE Network, and I use other free services too. The Business Edition packages add ESET Remote Sep 12, 2021 · This software Serial Vuescan Gmail and Password, Number is the best one. Activate Watch TCM Customer Satisfaction Is A Priority For Toshiba. Watch full episodes, specials and documentaries with National Geographic TV channel online. Plug one end of the phone cable into your phone and the other into your modem’s port labeled Voice 1. office 2019pro plus office 2019 product key oundo defrag 24 mulab 6. 00635510693109. Competition - blown away. 5. I might have ti ask for a refund. Start the process. 8. and privacy. 6 out of 5 stars 159 Version: 3. Your automatic standby generator requires activation in order to operate automatically. Activate, update or deactivate your UiPath license and automate seamlessly at any speed and scale. After it has settled down you should have a Win10 Pro OS but it will be in an unactivated state. Stream 100s of channels and 1000 The space labeled "username" in capital letters is where you enter the name you use when you log on to your computer. Removing your Google activation lock from device settings on your phone Depending on the exact model of the Android phone, the steps to remove your Google account may differ slightly. Let's activate your device. In this case, you need to install and activate a KMS server. 2. For anyone else, it’s . This service will suit you if you are Shrew Soft Vpn Access Manager Activation Key looking to access geo-restricted content from anywhere in the world. Fullscreen (f) Watch on Twitch. Portable generators, pressure washers, and transfer switches do not require activation. So without further ado, let’s get rolling. Go to Explorer and right-click on C:\Windows and click on the Security tab. Once you are a member you will sign in to the members area and get instant access to thousands of live TV channels, on-demand shows, movies, music, and more…. This is a free service with an option to get more channels by paying a premium fee, and though their premium subscription sounds tempting, you could do very well just with their free channels. Key for another application error TV brand 5 digit Comcast remote code; 3M: 10737 11616 11655 10724: 888: 14159: A-Mark: 10003 12286: Abex: 10032: Accurian: 11803: Acer: 12244 11339 12245 14143 Code Activation. Comedy central, AMC, CW15, CNBC, Syfy, Spike - all in hd now. Oct 21, 2021 · While holding the VCR/DVD button, press 2 for a VCR or 3 for a DVD player. 10. This change allows you to install Windows XP with Service Pack 3 on any PC without entering a product key and use it in trial mode until the 30-day activation grace period expires. This is a simple one-time process that only takes a few minutes and will also serve as the product registration. Video Game. An efficient blocker: Fast, potent and lean, and yet can load and enforce thousands more filters than other popular blockers out there. Enter your tracking number in the box below. Aug 22, 2009 · However, beginning 1 March 2005, the Product Key supplied on a label by the computer manufacturer, and used for the initial installation, will not be accepted for activation. Activate. After an online activation on the Product Activation server, the application can be used on this PC and four activations are left for this serial number. Another extraordinary database for serial keys and serials splits, serialbay. 2 serial number ccleaner bandicut serial number 2. Supra provides a cutting edge electronic lockbox system to the real estate industry. Oscars Best Picture Winners Best Picture Winners Golden Globes Emmys Hispanic & Latino Voices STARmeter Awards San Diego Comic-Con New York Comic-Con Sundance Film Festival Toronto Int'l Film Festival Awards Central Festival Central All EventsThis is a list of the best serials, hybrid serial, and Anthology series of all time. If you have any problems activating or using your software, please call technical support M-F, 9am-9pm MST, at 888-521-8959, and enter 37219 when prompted for your code. Locke & Key: Created by Meredith Averill, Aron Eli Coleite, Carlton Cuse. When I sign into the licensing portal it says there are "No products associated with my account. If you couldn’t find the key code which works for the device at that time you can setup your universal remote to search mode for the correct one. Once you have a 7-character activation code, go to fxnetworks. JustWatch is there to help you find all the shows you can stream legally in New-Zealand and make your life easier. Select your country to see the contact information of ABBYY offices or partners with which you can activate your program by phone or fax. Find the right VR Headset & Best VR Experiences. DESCRIPTION. MSNBC is a paid-for cable television news channel based in the United States of America. Jan 27, 2019 · Serial Key Finder Sites Platforms to Find Serial Keys For Software 1. Tableau Desktop detects that you are offline and shows the following message. 83% Upvoted. 1 updated from the Store. 99 per Jun 08, 2021 · THANK YOU! — Inside (@inside) June 9, 2021. SATA is the de facto standard for PC storage. Get it Sunday, October 31 - Monday, November 1. Step 3. You can upload IPTV channels playlist as m3u file or as a link. Get help with Windows activation errors. Click continue to visit your provider's website and verify your account . Ordered via call centre. This service lets you upload your key to Yubico's validation servers so that third-party services can authenticate you with Yubico OTP. Click continue to visit your provider's website and verify your account Key Survey’s online survey software helps you monitor and encourage employee engagement. 2. If Windows 10 was previously activated on your device, your copy of Windows 10 will be activated automatically. It was released internationally in 2016 on Netflix. Easy on CPU and memory. My cousin has also dumped an ISO image of the disk he used to install (Windows 7 Ultimate SP1, he told me) on my hard disk. activation. No matter which DISH remote control you have, you can easily turn your TV on and off, control the volume, access the guide, record programs, and tune to a specific channel. Abrams, the creator of Lost and Alias, teams up with Roberto Orci and Alex Kurtzman (Mission: Impossible 3, Transformers) to create this highly anticipated drama series. Windows 10 Activation Key free download - Windows Product Key Viewer/Changer, PDF Reader for Windows 10, Facebook for Windows 10, and many more programs STEP 1: Turn on the component you want to activate. Emmy Award winner Patricia Arquette stars as DuBois, a strong-willed, devoted young wife and mother of three Watch Fox News Channel, Fox Business Network, and FoxNews. DoestheV-ChipturnoffwhenIturn mytelevisionoff? Turning the television off will not turn off the V-Chip. CTV has all you need to watch the best TV. Explore hundreds of VR games & apps. Watch full episodes of current and classic USA shows online. SecureX unifies visibility, enables orchestration and automation, and strengthens security across endpoints, cloud, network, and apps. Steo 1. https:// support. If the problem occurs after you activate the key on the 4th, 5th, 6th etc. This is why I have curated a list of best sites for streaming TV shows for free One of Us is a British drama television miniseries created and written by Harry and Jack Williams for the BBC. Jul 28, 2021 · Run Settings > Update & Security > Activation; Verify that Activation is "Windows is not activated". Catch up TV. Crete is Greece's largest and most populous island All retail software uses a serial number or activation key of some form, and the . Activation Product Key & Serial Numbers can be a tricky topic, our expert technician Generate Product Keys & provide SoftwareWindows 7 Activation Key free download - Windows 7 (Professional), PDF Reader for Windows 7, Windows 7 (Ultimate), and many more programs. Step 2. FHD. For Vuescan License Key, scanners however with our apparatus. For each of our businesses, we consider customer support, satisfaction and feedback an essential element of our overall marketing effort. Then grab the black phone cable from your kit. Hold down the Power button along with the button for the item for which you want to program your remote. Activate Tubi on your Roku, Chromecast, Apple TV, Playstation, or Xbox device and start watching free movies and TV shows. Depending on your region, you can either phone the nearest ABBYY office or partner and provide your Installation ID and serial number to You will be directed to the PayPal website. You don't have to worry about being traced anymore. For any queries, Write us to [email protected] Find your IMEI number on your Apple devices. 88 (after 30% Aug 21, 2021 · In this article, you’re going to learn about the Avast SecureLine VPN license key, its activation code, and license file. 0 Hub 3 Ports , 2724595945826. Oct 04, 2021 · Step 4: Go through the activation link https://trakt. rar (727,02 Mb) En Modo Gratuito Turbobit. Step 5: Login in to your Trakt. J. If the key is valid, you get an active If you have an account with a participating cable/satellite/digital TV provider, you can link it to the NBC and NBCU family of apps to unlock all episodes in the library and access a live stream of your local station. Click continue to visit your provider's website and verify your account Scroll down to the IMEI, ESN, or MEID number. All Rights Reserved. Windows 10 Pro Multi-language, Life time Activation, DVD media plus License Key Sticker. This WPA key is case sensitive so please make sure to type the key exactly like shown on the TV including the lower or upper case. Let us know what you think of the site and tell us what features you want to see next. In the Account menu, select “ TV Provider ” and click the “ Sign In ” button. 0 out of 5 stars. You can easily catch All Blacks Rugby live Game from anywhere . mil Ensure you have your decoder's unique indentification numbers, found on the label of the decoder, when contacting the helpdesk. Note: If you were assigned an AT&T Access ID when you signed up for service, you don't need to create an account. Aug 19, 2021 · Table of Contents. Video service algorithms reward videos that are easy to click on, easy to watch, and easy to share, because that’s what makes them money. Watch positive, uplifting content live & on-demand!Earthquake strikes Greek island of Crete, killing one and injuring nine, General Secretariat for Civil Protection tells CNN. Hit the power button and connect to your network to watch hit movies, binge-worthy TV shows, the latest news, sports, comedy and more! Please note: channel and title availability subject to change. When prompted, enter your email address: If you already have a Roku account, log in using the email address associated with your account. Verify your account by inputting two of the three required fields below. Select “Activate a Product” and enter your code. Aug 13, 2020 · Microsoft Activation Scripts (MAS) 1. Method 3: Configure a KMS host server. Email. Watch full-length episodes of Grey's Anatomy, Station 19, Big Sky, The Voice, La Brea, Queens, JANN and more. Unlike other news channels, it’s availability is more focused on key markets such as United States, Canada, South Africa, Kenya, Northern Africa, and the Middle East. ESET NOD32 Antivirus is sold in two editions, Home Edition and Business Edition. The Virus is called: Personal Security. Ham Radio Deluxe Guides and Manuals. Unless you desire to print and read over 250 pages of user guide, we recommend visiting the wiki directly

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Verizon prepaid plans make it easy to purchase a new phone online. Simply pick which Verizon prepaid phone you want and pay the Verizon prepaid price. You’ll get a waived activation fee, and your SIM card sent free in the mail. Enjoy even more Verizon deals when signing up for the AutoPay feature on your Verizon prepaid plans. All Verizon plans are suited to fit any customer. From unlimited plans to kids’ plans and international plans, use a Verizon promo code to save on devices for everyone! 

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Take advantage of Verizon trade-in to save on your next phone upgrade! Simply go online and let them know what type of phone you currently have and they’ll tell you the estimated trade-in value. Get a Verizon discount on your next purchase, a Verizon gift card, or opt to receive a PayPal credit immediately. Check for other Verizon offers on their website to see how you can save even more on your phone plan! 

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Shop for new smartphones with great deals and feel confident in your purchase by reading customer Verizon reviews on each phone that they offer! Check out their deals section for constant Verizon offers such as the Verizon Bring Your Own Device or one of their Verizon plans for seniors. They have BOGO deals, free subscription additions, and more Verizon sales for you to choose from! You may also sign up for the Verizon rewards program for exciting, members-only Verizon discounts and news on upcoming products.

Upgrade your service carrier to experience quality care, the best devices, stress-free phone repair, an unlimited hotspot, and huge savings when you pick a plan with one of our Verizon coupons! You can even shop for useful accessories like a Verizon cell phone booster. No matter if you're looking for a new phone or just shopping around for Verizon plans, you can always enjoy amazing savings with sales, special offers and Verizon promo codes.

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Black Friday is the best time to score a great deal on a brand new smartphone or shiny new plan, and with Verizon Black Friday deals, you’ll save tons when you make the switch, upgrade your current contract, or take advantage of their Verizon add a line feature!

In previous years, Verizon offered its customers a serious way to save some cash: they offered $400 off the latest Apple and Android models, buy one get one free on the iPhone X or Samsung Galaxy S9, as well as $750 off any other iPhone model both in-store and online. Hopefully Verizon will provide a similar deal in 2021 on the newest smartphones of the year, so make sure you keep your eyes open to score some awesome tech!

This is also a great opportunity to purchase Verizon Protect, allowing you to receive repairs, replacements, identify theft monitoring, and more for a fraction of the full cost. We can also expect great Verizon discounts on fun accessories like phone cases, headphones, PopSockets, and other essentials, so you can get a new phone with all the bells and whistles at a super-low price this Black Friday.

Previous Verizon Discount Codes

Discount TypeCoupon Codes & DealsDiscount AmountStatus
Online CouponVerizon promo code free activationFree ActivationExpired
Online DealFree shipping on VerizonFree ShippingOngoing
Online CouponVerizon - $100 off coupon$100 OffExpired
Online CouponVerizon PrePaid phones promo code for 10% off
10% OffExpired
Online CouponVerizon promo code for $250 off when you upgrade$250 OffExpired
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Windows 11

Personal computer operating system by Microsoft released in 2021

Windows 11 logo.svg
Windows 11 Desktop.png

Screenshot of Windows 11, showing the new Start menu and centered taskbar[1]

DeveloperMicrosoft
Written in
OS familyMicrosoft Windows
Source model
Released to
manufacturing
October 5, 2021; 46 days ago (2021-10-05)
General
availability
October 5, 2021; 46 days ago (2021-10-05)[6]
Latest release21H2 (10.0.22000.318) (November 9, 2021; 11 days ago (2021-11-09)[7]) [±]
Latest preview10.0.22504.1010 (November 19, 2021; 1 day ago (2021-11-19)[8]) [±]
Marketing targetPersonal computing, tablets
Available in110 languages[9][10]

List of languages

Update method
Platformsx86-64, ARM64
Kernel typeHybrid (Windows NT kernel)
UserlandNative API
Windows API
.NET Framework
Universal Windows Platform
Windows Subsystem for Linux
Default
user interface
Windows shell (graphical)
Preceded byWindows 10 (2015)
Official websitewww.microsoft.com/windows/windows-11Edit this at Wikidata
See § Versions for details.

Windows 11 is a major release of the Windows NToperating system developed by Microsoft that was announced on June 24, 2021, and is the successor to Windows 10, which was released in 2015. Windows 11 was released to the public on October 5, 2021, as a free upgrade via Windows Update and Windows 11 Installation Assistant on eligible devices running Windows 10.

Windows 11 features major changes to the Windows shell influenced by the canceled Windows 10X, including a redesigned Start menu, the replacement of its "live tiles" with a separate "Widgets" panel on the taskbar, the ability to create tiled sets of windows that can be minimized and restored from the taskbar as a group, and new gaming technologies inherited from Xbox Series X and Series S such as Auto HDR and DirectStorage on compatible hardware. Internet Explorer (IE) has been replaced by the Chromium-based Microsoft Edge as the default web browser (for compatibility[11][12] with Google Chrome web browser[13]), and Microsoft Teams is integrated into the Windows shell. Microsoft also announced plans to allow more flexibility in software that can be distributed via Microsoft Store, and to support Androidapps on Windows 11 (including a partnership with Amazon to make its app store available for the function.

Citing security considerations, the system requirements for Windows 11 were increased over Windows 10. Microsoft only officially supports the operating system on devices using an eighth-generationIntel Core CPU or newer (with some exceptions), AMD Ryzen CPU based on Zen+ microarchitecture or newer, or a Qualcomm Snapdragon 850ARMsystem-on-chip or newer, with UEFI secure boot and Trusted Platform Module (TPM) 2.0 supported and enabled (although Microsoft may provide exceptions to the TPM 2.0 requirement for OEMs). While the OS can be installed on unsupported processors, Microsoft does not guarantee the availability of updates. Windows 11 also drops support for 32-bitx86 CPUs and devices which use BIOS firmware.

Windows 11 has received a mixed to positive reception; pre-release coverage of the operating system focused on its stricter hardware requirements, with discussions over whether they were legitimately intended to improve the security of Windows or a ploy to upsell users to newer devices, and over e-waste associated with the changes. Upon its release, Windows 11 received positive reviews for its improved visual design, window management, and stronger focus on security, but was panned for regressions and modifications to aspects of its user interface.

Development

At the 2015 Ignite conference, Microsoft employee Jerry Nixon stated that Windows 10 would be the "last version of Windows", a statement that Microsoft confirmed was "reflective" of its view.[14][15] The operating system was considered to be a service, with new builds and updates to be released over time.[16]

In October 2019, Microsoft announced "Windows 10X", a future edition of Windows 10 designed exclusively for dual-touchscreen devices such as the then-upcoming Surface Neo. It featured a modified user interface designed around context-sensitive "postures" for different screen configurations and usage scenarios, and changes such as a centered taskbar and updated Start menu without Windows 10's "live tiles". Legacy Windows applications would also be required to run in "containers" to ensure performance and power optimization. Microsoft stated that it planned to release Windows 10X devices by the end of 2020.[17][18][19]

In May 2020, amid the COVID-19 pandemic, chief product officer for Microsoft Windows and OfficePanos Panay stated that "as we continue to put customers' needs at the forefront, we need to focus on meeting customers where they are now", and therefore announced that Windows 10X would only launch on single-screen devices at first, and that Microsoft would "continue to look for the right moment, in conjunction with our OEM partners, to bring dual-screen devices to market".[20][21]

In January 2021, it was reported that a job listing referring to a "sweeping visual rejuvenation of Windows" had been posted by Microsoft.[22] A visual refresh for Windows, developed under the codename "Sun Valley", was reportedly set to re-design the system's user interface.[23] Microsoft began to implement and announce some of these visual changes and other new features on Windows 10 Insider Preview builds, such as new system icons (which also included the replacement of shell resources dating back as far as Windows 95),[24] improvements to Task View to allow changing the wallpaper on each virtual desktop, emulation of x64 applications on ARM, and adding the Auto HDR feature from Xbox Series X.[25][26]

On May 18, 2021, Head of Windows Servicing and Delivery John Cable stated that Windows 10X had been canceled, and that Microsoft would be "accelerating the integration of key foundational 10X technology into other parts of Windows and products at the company".[27]

Announcement

At the Microsoft Build 2021 developer conference, CEO and chairman Satya Nadella teased about the existence of the next generation of Windows during his keynote speech. According to Nadella, he had been self-hosting it for several months. He also teased that an official announcement would come very soon.[28] Just a week after Nadella's keynote, Microsoft started sending invitations for a dedicated Windows media event at 11 am ET on June 24, 2021.[29][30] Microsoft also posted an 11-minute video of Windows start-up sounds to YouTube on June 10, 2021, with many people speculating both the time of the Microsoft event and the duration of the Windows start-up sound video to be a reference to the name of the operating system as Windows 11.[31][32]

On June 24, 2021, Windows 11 was officially announced at a virtual event hosted by Chief Product OfficerPanos Panay.[33][34][35] According to Nadella, Windows 11 is "a re-imagining of the operating system".[36] Further details for developers such as updates to the Microsoft Store, the new Windows App SDK (code-named "Project Reunion"), new Fluent Design guidelines, and more were discussed during another developer-focused event on the same day.[37][38][39]

Release

The Windows 11 name was accidentally released in an official Microsoft support document in June 2021.[40][41] Leaked images of a purported beta build of Windows 11's desktop surfaced online later on June 15, 2021,[42][43] which were followed by a leak of the aforementioned build on the same day.[44] The screenshots and leaked build show an interface resembling that of the canceled Windows 10X, alongside a redesigned out-of-box experience (OOBE) and Windows 11 branding.[45] Microsoft would later confirm the authenticity of the leaked beta, with Panay stating that it was an "early weird build".[46][47]

At the June 24 media event, Microsoft also announced that Windows 11 would be released in "Holiday 2021", with an exact date not given.[48][49] Its release will be accompanied by a free upgrade for compatible Windows 10 devices through Windows Update.[50] On June 28, Microsoft announced the release of the first preview build and SDK of Windows 11 to Windows Insiders.[51]

On August 31, 2021, Microsoft announced that Windows 11 was to be released on October 5, 2021.[52] The release would be phased, with newer eligible devices to be offered the upgrade first.[6] Since its predecessor Windows 10 was released on July 29, 2015, more than six years earlier, this is the longest time span between successive releases of Microsoft Windows operating systems, beating the time between Windows XP (released on October 25, 2001) and Windows Vista (released on January 30, 2007).[53]

Microsoft officially released Windows 11 on October 4, 2021, at 2:00 p.m. PT, which was October 5 in parts of the world.[54] It can be obtained as an in-place upgrade via either the Windows 11 Installation Assistant application (the successor to the Media Creation Tool from Windows 10, which can also generate an ISO image or USB install media), or via Windows Update on eligible devices.[55]

Updates through Windows Update are a phased rollout, and are distributed on an opt-in basis: Microsoft stated that they "expect all eligible Windows 10 devices to be offered the upgrade to Windows 11 by mid-2022."[56][57] Eligible devices also may present an option to download Windows 11 during the Windows 10 out-of-box experience (OOBE) on a new installation.[58]

Features

Main article: Features new to Windows 11

See also: List of features removed in Windows 11

Windows 11, the first major Windows release since 2015, builds upon its predecessor by revamping the user interface to follow Microsoft's new Fluent Design guidelines. The redesign, which focuses on ease of use and flexibility,[50] comes alongside new productivity and social features and updates to security and accessibility, addressing some of the deficiencies of Windows 10.[59]

The Microsoft Store, which serves as a unified storefront for apps and other content, is also redesigned in Windows 11. Microsoft now allows developers to distribute Win32, progressive web applications, and other packaging technologies in the Microsoft Store, alongside Universal Windows Platform apps.[60] Microsoft also announced plans to allow third-party application stores (such as Epic Games Store) to distribute their clients on Microsoft Store.[61] Windows 11 supports x86-64 software emulation on ARM-based platforms.[62]

The collaboration platform Microsoft Teams is integrated into the Windows 11 user interface, and is accessible via the taskbar. Skype will no longer be bundled with the OS by default.[63][64][65]

Microsoft claims performance improvements such as smaller update sizes, faster web browsing in "any browser", faster wake time from sleep mode, and faster Windows Hello authentication.[63][66]

Windows 11 ships with the Chromium-based Microsoft Edgeweb browser, and does not include or support Internet Explorer.[67] Its rendering engine Trident is still included with the operating system for backwards compatibility reasons, and Edge can be configured with Group Policy to render whitelisted websites in "IE Mode" (which still uses IE's rendering engine Trident, instead of Blink layout engine).[68] Windows 11 is the first version of Windows since the original retail release of Windows 95 to not ship with (the full version of) Internet Explorer.[69]

The updated Xbox app,[70][71] along with the Auto HDR and DirectStorage technologies introduced by the Xbox Series X and Series S, will be integrated into Windows 11; the latter requiring a graphics card supporting DirectX 12 and an NVMesolid-state drive.[71][72]

User interface

A redesigned interface is present throughout the operating system, building upon Fluent Design System; translucency, shadows, a new color palette, and rounded geometry are prevalent throughout the UI. A prevalent aspect of the design is an appearance known as "Mica", described as an "opaque, dynamic material that incorporates theme and desktop wallpaper to paint the background of long-lived windows such as apps and settings".[73][74] Much of the interface and start menu take heavy inspiration from the now-canceled Windows 10X. The Segoe UIfont used since Windows Vista has been updated to a variable version, improving its ability to scale between display resolutions.[76]

The taskbar's buttons are center-aligned by default, and it is permanently pinned to the bottom edge of the screen; it cannot be moved to the top, left, or right edges of the screen as in previous versions of Windows.[77] The notifications sidebar is now accessed by clicking the date and time, with other Quick Actions toggles, as well as volume, brightness, and media playback controls, moved to a new settings pop-up displayed by clicking on the system tray. The "Widgets" button on the taskbar displays a panel with Microsoft Start,[78] a news aggregator with personalized stories and content (expanding upon the "news and interests" panel introduced in later builds of Windows 10).[66][73]Microsoft Teams is similarly integrated with the taskbar, with a pop-up showing a list of recent conversations.[65]

The Start menu has been significantly redesigned, replacing the "live tiles" used by Windows 8.x and 10 with a grid of "pinned" applications, and a list of recent applications and documents.[63][66]File Explorer was updated to replace its ribbon toolbar with a more traditional toolbar, while its context menus have been redesigned to move common tasks (such as copy and paste) to a toolbar along the top of the menu, and hide advanced operations under an overflow menu.[73]

Task View, a feature introduced in Windows 10, features a refreshed design, and supports giving separate wallpapers to each virtual desktop. The window snapping functionality has been enhanced with two additional features; hovering over a window's maximize button displays pre-determined "Snap Layouts" for tiling multiple windows onto a display, and tiled arrangement of windows can be minimized and restored from the taskbar as a "snap group".[66][79] When a display is disconnected in a multi-monitor configuration, the windows that were previously on that display will be minimized rather than automatically moved to the main display. If the same display is reconnected, the windows are restored to their prior location.[80]

Windows Subsystem for Android

Further information: Project Astoria and Windows Subsystem for Linux

On October 21, 2021, Windows Subsystem for Android (WSA) became available to Beta channel builds of Windows 11 for users in the United States,[81] which allows users to install and run Android apps. Users can install Android apps through any source using the Android application package (APK) file format.[82] An Amazon Appstore client for Microsoft Store will also be available.[83][84][85][86]

WSA is based on the Intel Bridge runtime compiler; Intel stated that the technology is not dependent on its own CPUs, and will also be supported on x86-64 and ARM CPUs from other vendors.[86]

System security

As part of the minimum system requirements, Windows 11 only runs on devices with a Trusted Platform Module 2.0 security coprocessor.[87][88] According to Microsoft, the TPM 2.0 coprocessor is a "critical building block" for protection against firmware and hardware attacks. In addition, Microsoft now requires devices with Windows 11 to include virtualization-based security (VBS), hypervisor-protected code integrity (HVCI), and Secure Boot built-in and enabled by default.[89] The operating system also features hardware-enforced stack protection for supported Intel and AMD processors for protection against zero-day exploits.

Like its predecessor, Windows 11 also supports multi-factor authentication and biometric authentication through Windows Hello.[89]

Versions

Main article: Windows 11 version history

Windows 11 is available in two main editions; the Home edition is intended for consumer users, while the Pro edition contains additional networking and security features (such as BitLocker), as well as the ability to join a domain.[90] Windows 11 Home may be restricted by default to verified software obtained from Microsoft Store ("S Mode").[91] Windows 11 Home requires an internet connection and Microsoft account in order to complete first-time setup.[92]

Windows 11 SE was announced on November 9, 2021, as an edition exclusively for low-end devices sold in the education market, and a successor to Windows 10 S. It is designed to be managed via Microsoft Intune, and has changes based on feedback from educators to simplify the user interface and reduce "distractions", such as Snap Layouts not containing layouts for more than two applications at once, all applications opening maximized by default, Widgets being removed, and Microsoft Edge being configured by default to allow extensions from Chrome Web Store (primarily to target those migrating from Chrome OS). It is bundled with applications such as Microsoft Office for Microsoft 365, Minecraft Education Edition, and Flipgrid, while OneDrive is used to save files by default. Windows 11 SE does not include Microsoft Store; third-party software is provisioned or installed by administrators.[93][94]

The Windows Insider program carries over from Windows 10, with pre-release builds divided into "Dev" (unstable builds used to test features for future feature updates), "Beta" (test builds for the next feature update; relatively stable in comparison to Dev channel), and "Release Preview" (pre-release builds for final testing of upcoming feature updates) channels.[95]

System requirements

The basic system requirements of Windows 11 differ significantly from Windows 10. Windows 11 only supports 64-bit systems such as those using an x86-64 or ARM64 processor; IA-32 processors are no longer supported.[88] Thus, Windows 11 is the first consumer version of Windows not to support 32-bit processors and 16-bit software (though Windows Server 2008 R2 was the first version of Windows NT to not support them).[98][99] The minimum RAM and storage requirements were also increased; Windows 11 now requires at least 4GB of RAM and 64GB of storage. S mode is only supported for the Home edition of Windows 11.[100] As of August 2021, the officially supported list of processors includes Intel Core 8th generation and later, AMD Zen+ and later (which include the "AF" revisions of Ryzen 1000 CPUs, which are underclocked versions of Zen+-based Ryzen 2000 parts that supplant Ryzen 1000 parts that could no longer be manufactured due to a change in process),[101] and Qualcomm Snapdragon 850 and later.[102] The compatibility list includes the Intel Core i7-7820HQ, a seventh-generation processor used by the Surface Studio 2,[103] although only on devices that shipped with DCH-based drivers.[104]

Legacy BIOS is no longer supported; a UEFI system with Secure Boot and a Trusted Platform Module (TPM) 2.0 security coprocessor is now required.[77][105][106][107] The TPM requirement in particular has led to confusion as many motherboards do not have TPM support, or require a compatible TPM to be physically installed onto the motherboard. Many newer CPUs also include a TPM implemented at the CPU level (with AMD referring to this "fTPM", and Intel referring to it as "Platform Trust Technology" [PTT]),[108] which might be disabled by default and require changing settings in the computer's UEFI firmware,[109] or an UEFI firmware update that is configured to automatically enable the firmware TPM upon installation.[110]

Original equipment manufacturers can still ship computers without a TPM 2.0 coprocessor upon Microsoft's approval.[111][112] Devices with unsupported processors are not blocked from installing or running Windows 11; however, a clean install or upgrade using ISO installation media must be performed as Windows Update will not offer an upgrade from Windows 10.[113] Additionally, users must also accept an on-screen disclaimer stating that they will not be entitled to receive updates, and that damage caused by using Windows 11 on an unsupported configuration are not covered by the manufacturer's warranty.[114][115] Some third-party software may refuse to run on unsupported configurations of Windows 11.[116]

Reception

Pre-release

Reception of Windows 11 upon its reveal was positive, with critics praising the new design and productivity features.[117] However, Microsoft was criticized for creating confusion over the minimum system requirements for Windows 11.[118] The increased system requirements (compared to those of Windows 10) initially published by Microsoft could see as many as 60 percent of existing Windows 10 PCs unable to upgrade to Windows 11,[119] which has faced concerns that this will make the devices electronic waste.[120]

It has been theorized that these system requirements were a measure intended to encourage the purchase of new PCs, especially amid a downturn in PC sales and increased prices due to the global chip shortage.[73] While Microsoft has not specifically acknowledged this when discussing the cutoff, it was also acknowledged that the sixth and seventh generation of Intel Core processors were prominently afflicted by CPU-level security vulnerabilities such as Meltdown and Spectre, and that newer CPUs manufactured since then had increased mitigations against the flaws.[73][121] Research Vice President of Gartner Stephen Kleynhans felt that Microsoft was "looking at the entire stack from the hardware up through the applications and the user experience and trying to make the entire stack work better and more securely.[121]

Launch

Andrew Cunningham of Ars Technica praised the improvements to its visual design (describing the new "Mica" appearance as reminiscent of the visual appearance of iOS and macOS, and arguing that Microsoft had "[made] a serious effort" at making the user-facing aspects of Windows 11 more consistent visually), window management, performance (assessed as being equivalent to if not better than Windows 10), other "beneficial tweaks", and its system requirements having brought greater public attention to hardware security features present on modern PCs. Criticism was raised towards Widgets' lack of support for third-party content (thus limiting it to Microsoft services only), regressions in taskbar functionality and customization, the inability to easily select default applications for common tasks such as web browsing (now requiring the user to select the browser application for each file type individually), and Microsoft's unclear justification for its processor compatibility criteria. Cunningham concluded that "as I've dug into [Windows 11] and learned its ins and outs for this review, I've warmed to it more", but argued that the OS was facing similar "public perception" issues to Windows Vista and Windows 8. However, he noted that 11 did not have as many performance issues or bugs as Vista had upon its release, nor was as "disjointed" as 8, and recommended that users who were unsure about the upgrade should stay on Windows 10 in anticipation of future updates to 11.[73]

Tom Warren of The Verge described Windows 11 as being akin to a house in the middle of renovations, but that "actually using Windows 11 for the past few months hasn't felt as controversial as I had expected"—praising its updated user interface as being more modern and reminiscent of iOS and Chrome OS, the new start menu for feeling less cluttered than the Windows 10 iteration, updates to some of its stock applications, and Snap Assist. Warren noted that he rarely used the Widgets panel or Microsoft Teams, citing that he preferred the weather display that later versions of Windows 10 offered, and didn't use Teams to communicate with his friends and family. He also acknowledged the expansion of Microsoft Store to include more "traditional" desktop applications. However, he felt that Windows 11 still felt like a work in progress, noting UI inconsistencies (such as dark mode and new context menu designs not being uniform across all dialogues and applications, and the modern Settings app still falling back upon legacy Control Panel applets for certain settings), regressions to the taskbar (including the inability to move it, drag files onto taskbar buttons in order to focus the corresponding application, and the clock only shown on the primary display in multi-monitor configurations), and promised features (such as dynamic refresh rate support and a universal microphone mute button) not being present on the initial release. Overall, he concluded that "I wouldn't rush out to upgrade to Windows 11, but I also wouldn't avoid it. After all, Windows 11 still feels familiar and underneath all the UI changes, it's the same Windows we've had for decades."[122]

PC World was more critical, arguing that Windows 11 "sacrifices productivity for personality, but without cohesion", commenting upon changes such as the inability to use local "offline" accounts on Windows 11 Home, regressions to the taskbar, a "functionally worse" start menu, Microsoft Teams integration having privacy implications and being a ploy to coerce users into switching to the service, File Explorer obscuring common functions under unclear icons, using "terribly sleazy" behaviors to discourage changing the default web browser from Microsoft Edge, and that the OS "anecdotally feels less responsive, slower, and heavier than Windows 10." It was concluded that Windows 11 "feels practical and productive, but less so than its predecessor in many aspects", while its best features were either "hidden deeper within", required specific hardware (DirectStorage, Auto HDR) or were not available on launch (Android app support).[123]

See also

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    Frequently asked questions about the Accellion data breach

    The University of California Undergraduate Experience Survey (UCUES) solicits student opinions on a broad range of academic and co-curricular experiences, including instruction, advising and student services. UCUES provides information about student attitudes and behaviors including time use, academic engagement and community involvement. It assesses attitudes towards many different aspects of campus life including academic advising, campus climate, courses & instruction, and interaction with faculty. It documents students' self-perceptions and goals, political beliefs, and perceptions of the role of the research university. It also collects background demographic information, such as first language, family immigration background and social class.

    +

    Why does UC conduct the UCUES?

    UCUES has been used extensively to guide the University on improving the undergraduate experience. Campuses also use UCUES to report on the quality of their academic programs to their academic senates. Some campuses have used UCUES data in their WASC accreditation self-studies. Other campuses, as well as the Council of Vice-Chancellors of Student Affairs, use UCUES to evaluate the quality and use of their student services. A number of campuses have used UCUES to report on campus climate and the impact of diversity on students' educational experiences.

    UCUES data and results have been used in UC’s Annual Accountability Reports, UC Budget for Current Operations, and to inform regents' committees, such as the Long-Range Guidance Team, the Diversity Study Group, and Student Basic Needs Committee.

    +

    Was other survey data impacted by the Accellion FTA security event?

    We have not identified any other impacted surveys.

    +

    What types of information from the UCUES survey were posted to the internet?

    The impacted information includes participants’ full survey responses, which potentially include your name; email address; student ID; background and personal characteristics; academic engagement; educational experiences; personal development and mental health; the campus climate for diversity and inclusiveness; sexual misconduct situations; student life; and food and housing security, if you provided this information in response to the survey. A sample list of the questions from the survey can be found here.

    The University used the Accellion FTA to transfer large files such as the survey results.  Unfortunately, perpetrators exploited a vulnerability in the application and attacked over 100 organizations including universities, government agencies, and private companies. When the University discovered the issue, we took the system offline and patched the Accellion vulnerability. We are in the process of transitioning to a more secure solution. The University cooperated with the FBI and worked with external cybersecurity experts to investigate this matter and determine what happened, what data was impacted, and to whom the data belongs.

    When the University discovered the issue, it took the Accellion FTA offline and patched the vulnerability. There is no evidence that other University systems were impacted. The University is in the process of transitioning to a new file transfer system with enhanced security controls, deploying additional system monitoring broadly throughout its network, conducting a security health check of certain systems, and enhancing security controls, processes, and procedures.

    +

    How does the University intend to protect the confidentiality of those that take the UCUES going forward?

    When the University discovered that student responses gathered in the 2020 University of California Undergraduate Experiences Survey (UCUES) were, unfortunately, part of the data in the Accellion FTA at the time of the cyberattack and posted to the internet, it began reviewing the policies and procedures surrounding the biennial survey to better protect the personal data and privacy of the UC community. That process to strengthen these policies and procedures is ongoing.

    +

    What resources does the University have if I’m concerned about my physical, mental or emotional well-being?

    There are several mental and emotional health support and safety resources available across the University community:  

    • Counseling & Psychological Services– Confidential mental and emotional health support is available for students through the appropriate counseling and psychological services office (sometimes called CAPS) for your campus:  
    • Faculty & Staff Assistance Program– Each campus, medical center, and national laboratory within the University administers its own faculty and staff assistance program (sometimes called an Employee Assistance Program). Assistance programs offer free, confidential resources for emotional health, often available right on campus, with easy access to short-term counseling, assessment, and referral. For more information on assistance programs available at specific UC locations, click here. 
    • CARE– For survivors of sexual violence, intimate partner violence, or stalking, please contact a UC CARE Advocate for confidential, compassionate support and safety planning. For more information about your campus CARE office, click here. If you’re in danger or need help now, call 9-1-1.  

    If you need support beyond the UC community, these offices can also provide information about potential local resources that are available.  

    +

    I am a 2021-2022 applicant to a University of California campus. Was my information affected?

    The contact information for individuals who started or completed the application process for the University of California for the 2021 – 2022 school year were impacted. That contact information is limited to names, email addresses, and phone numbers.

    The University is separately notifying these individuals, and their notification will contain information on what precautions they may take.

    +

    I am a 2020-2021 applicant to a University of California campus. Was my information affected?

    Information from submitted applications for the University of California for the 2020-2021 school year were impacted. This information could include date of birth, gender identity, family household income level, ethnicity and/or tribal affiliation and first language, sexual orientation, academic information (GPA, test scores), and whether you have received foster care.

    The University is separately notifying these individuals, and their notification contains information on what precautions they may take.

    +

    I am an applicant to the University of California (UC) system for the 2020-2021 and 2021-2022 academic year. What resources are available to me?

    The University is separately notifying 2020-2021 and 2021-2022 student applicants. Their notification contains information on what precautions they may take. 

    We ask that University community members remain vigilant against threats of identity theft or fraud.  Additionally, it is always a good idea to be on alert for “phishing” emails or phone calls by someone who acts like they know you or are part of a company that you may do business with, and requests sensitive information, such as passwords, Social Security numbers, or financial account information. You may report suspected phishing or social engineering attempts to communications@ucop.edu, or the following email addresses depending upon your campus:

    We also recommend that you rotate passwords and use multifactor authentication for your online accounts when offered.

    Источник: https://ucnet.universityofcalifornia.edu/data-security/updates-faq/index.html

    It is our commitment to you that you are comfortable with your investment. In light of these uncertain times, the Pirates are pledging to provide assurance to you that your investment in Pirates Baseball will be guaranteed.

    HEALTH AND SAFETY

    The Pirates are committed to implementing health and safety protocols to help minimize risk and maximize your experience at PNC Park. We will be taking the necessary steps and are focused on providing the highest-quality safety measures before, during, and after each game. To help create a safe experience at PNC Park, we are committed to, at minimum, implementing and adhering to the recommendations and guidelines set forth by public health officials.

    SEAT PROTECTION

    In the event your 2021 seats are impacted due to restricted capacity or a reduced number of regular season home games resulting from the pandemic, we will do everything possible to provide you the best seat location and season ticket plan that meets your expectation. If we are unable to meet that expectation, you will have the opportunity to use the money on your account towards a different ticket purchase in 2021, a credit for the 2022 season or a refund back to your initial payment method. In the event 2021 home games require reduced seating capacity, Pirates season ticket holders will be guaranteed seating opportunities before the general public.

    OTHER UPDATES

    We will continue to provide updates via email when we have any additional information. Please feel free to contact us at 1-800-BUY-BUCS (1-800-289-2827) or via email at [email protected].

    Источник: https://www.mlb.com/pirates/tickets/2021-ticket-information-waitlist
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    • Windows 10 Enterprise 2016 LTSB Product Key 2021             84NGF-MHBT6-FXBX8-QWJK7-DRR8H
    • Windows Pro N for Workstations Product Key 2021               NW6C2-QMPVW-D7KKK-3GKT6-VCFB2
    • Windows 10 Home Single Language Product Key 2021          8PTT6-RNW4C-6V7J2-C2D3X-MHBPB
    • Windows 10 Professional Workstation Product Key 2021       YVWGF-BXNMC-HTQYQ-CPQ99-66QFC
    • Windows 10 S Product Key 2021                                             GJTYN-HDMQY-FRR76-HVGC7-QPF8P
    • Windows 10 Home Country Specific Product Key 2021           YYVX9-NTFWV-6MDM3-9PT4T-4M68B
    • Windows 10 Education N Product Key 2021                           XGVPP-NMH47-7TTHJ-W3FW7-8HV2C
    • Windows 10 Enterprise Evaluation Product Key 2021              NPPR9-FWDCX-D2C8J-H872K-2YT43
    • Windows 10 Home Product Key 2021                                     MNXKQ-WY2CT-JWBJ2-T68TQ-YBH2V
    • Windows 10 Enterprise Product Key 2021                               NW6C2-QMPVW-D7KKK-3GKT6-VCFB2
    • Windows 10 Pro Product Key 2021                                          MNXKQ-WY2CT-JWBJ2-T68TQ-YBH2V
    • Windows 10 Education N Product Key 2021                            DCPHK-NFMTC-H88MJ-PFHPY-QJ4BJ
    • Windows 10 Education Key Product Key 2021                         WYPNQ-8C467-V2W6J-TX4WX-WT2RQ
    • Windows 10 Education Product Key 2021                                QFFDN-GRT3P-VKWWX-X7T3R-8B639
    • Windows 10 Enterprise Product Key 2021                                84NGF-MHBT6-FXBX8-QWJK7-DRR8H
    • Windows 10 Pro N Product Key 2021                                        2F77B-TNFGY-69QQF-B8YKP-D69TJ
    • Windows 10 Pro Product Key 2021                                           VK7JG-NPHTM-C97JM-9MPGT-3V66T
    • Windows 10 Home Product Key 2021                                       WNMTR-4C88C-JK8YV-HQ7T2-76DF9

    Latest Key for Updated 11th OCT 2021 full Working

     

    XWBNP-R777Q-94V43-P86KP-TMT6Y

    💻Windows 10 Enterprise
    🔑 VD4JD-N2FYT-HHTH6-TVVQT-9KXR4 (3513 users)
    🔑 RRPWN-69DBB-FDYV4-VTTYV-VT9R4 (1087 users)

    💻 Windows 10 PRO 
    🔑 XWBNP-R777Q-94V43-P86KP-TMT6Y (1141 users)
    🔑 Q87TN-WTDM8-TMGCX-DKD6W-MTDGY (23 users)

    Windows 10 Product Key

    • Windows 10 Pro Insider Preview build 10074, 10122, and 10130: 6P99N-YF42M-TPGBG-9VMJP-YKHCF
    • Windows 10 Core Insider Preview build 10158, 10159, 10162, and 10166: KTNPV-KTRK4-3RRR8-39X6W-W44T3
    • Windows 10 Technical Preview: NKJFK-GPHP7-G8C3J-P6JXR-HQRJR
    • Windows 10 Enterprise Insider Preview build 10074 and 10122: VTNMT-2FMYP-QCY43-QR9VK-WTVCK
    • Windows 10 Professional Insider Preview build 10158, 10159, 10162, and 10166: 8N67H-M3CY9-QT7C4-2TR7M-TXYCV
    • Windows 10 Professional build 1511: YTYG9-FR8RD-QBQC8-HC7J2-2JJFF

    Windows 10 LTSC/LTSB versions

    Windows 10 LTSC 2021

    Windows 10 LTSB 2016

    Windows 10 LTSB 2015

    Generate Key for Windows 10

    Note: This Product keys used only 2 users for 1 key our expired after 6 month its full tested Windows 10 keys latest 2020

    Windows 10 Home

    TX9XD-98N7V-6WMQ6-BX7FG-H8Q99

    Windows 10 Home Single Language

    7HNRX-D7KGG-3K4RQ-4WPJ4-YTDFH

    Windows 10 Home Country Specific (CN)

    PVMJN-6DFY6-9CCP6-7BKTT-D3WVR

    Windows 10 Home N

    3KHY7-WNT83-DGQKR-F7HPR-844BM

    Windows 10 Professional

    W269N-WFGWX-YVC9B-4J6C9-T83GX
    VK7JG-NPHTM-C97JM-9MPGT-3V66T
    8N67H-M3CY9-QT7C4-2TR7M-TXYCV

    Windows 10 Professional N

    MH37W-N47XK-V7XM9-C7227-GCQG9
    2B87N-8KFHP-DKV6R-Y2C8J-PKCKT

    Windows 10 Enterprise

    NPPR9-FWDCX-D2C8J-H872K-2YT43
    XGVPP-NMH47-7TTHJ-W3FW7-8HV2C
    CKFK9-QNGF2-D34FM-99QX3-8XC4K

    Windows 10 Enterprise N

    DPH2V-TTNVB-4X9Q3-TJR4H-KHJW4
    WGGHN-J84D6-QYCPR-T7PJ7-X766F

    Windows 10 Enterprise S

    FWN7H-PF93Q-4GGP8-M8RF3-MDWWW

    Windows 10 Education

    NW6C2-QMPVW-D7KKK-3GKT6-VCFB2
    YNMGQ-8RYV3-4PGQ3-C8XTP-7CFBY

    Windows 10 Education N

    2WH4N-8QGBV-H22JP-CT43Q-MDWWJ
    84NGF-MHBT6-FXBX8-QWJK7-DRR8H

    Windows 10 Enterprise 2015 LTSB

    WNMTR-4C88C-JK8YV-HQ7T2-76DF9

    Windows 10 Enterprise 2015 LTSB N

    2F77B-TNFGY-69QQF-B8YKP-D69TJ

    Windows 10 Core

    KTNPV-KTRK4-3RRR8-39X6W-W44T3

    Windows 10 Core Single Language

    BT79Q-G7N6G-PGBYW-4YWX6-6F4BT
    JPYNJ-XTFCR-372YJ-YJJ4Q-G83YB
    JPYNH-XTFCR-372YJ-YJJ3Q-G83YB
    R3BYW-CBNWT-F3JTP-FM942-BTDXY (CN)

    ESD ISO

    6P99N-YF42M-TPGBG-9VMJP-YKHCF

    Windows 10 Pro Product Key 2019

    The best windows OS brings you the foremost innovative tools and safety features that may not solely create your device secure however additionally permits you to perform your daily task in the most inventive and productive approach. Windows ten uses and combines some cool options of windows seven and windows eight that create it stand out from alternative Microsoft in operation Systems.

    W269N-WFGWX-YVC9B-4J6C9-T83GX
    FJT8C-2WNKT-DKPQG-JYHXD-YBFFC
    X4XQN-VMKJH-7TCVD-TB3QT-KTPKM
    3MXN9-Y96QV-RPYHW-RKQQJ-XW3GY
    NFKWT-HFWJW-93DP7-M3GMQ-FM49M
    NVTPG-P4YBM-KDH2X-GHQ99-66PKM
    NF3RK-PHM7C-8743J-X2X92-J44DB
    YW9TN-9M6H7-MKTJ4-H7FQW-4VV3B
    NCH3J-3Y32T-QY4Y9-4CDK3-C3726
    N24DD-FGXK3-2RWYX-6D87B-HT672

    Windows 10 Product Activation Keys (All Versions)

    In a terribly short amount of your time windows ten was able to capture the eye of the many peoples together with IT professionals, businessperson, and personnel referring to completely different fields. Before the official launch of windows, ten Microsoft has additionally discharged Technical preview of the Windows ten to draw in technical school knowledgeable and IT professionals.

    Windows Server 2016 Datacenter

    CB7KF-BWN84-R7R2Y-793K2-8XDDG

    Windows Server 2016 Standard

    WC2BQ-8NRM3-FDDYY-2BFGV-KHKQY

    Windows Server 2016 Essentials

    JCKRF-N37P4-C2D82-9YXRT-4M63B

    Windows 10 Professional

    W269N-WFGWX-YVC9B-4J6C9-T83GX

    Windows 10 Professional N

    MH37W-N47XK-V7XM9-C7227-GCQG9

    Windows 10 Enterprise

    NPPR9-FWDCX-D2C8J-H872K-2YT43

    Windows 10 Enterprise N

    DPH2V-TTNVB-4X9Q3-TJR4H-KHJW4

    Windows 10 Education

    NW6C2-QMPVW-D7KKK-3GKT6-VCFB2

    Windows 10 Education N

    2WH4N-8QGBV-H22JP-CT43Q-MDWWJ

    Windows 10 Enterprise 2015 LTSB

    WNMTR-4C88C-JK8YV-HQ7T2-76DF9

    Windows 10 Enterprise 2015 LTSB N

    2F77B-TNFGY-69QQF-B8YKP-D69TJ

    Windows 10 Enterprise 2016 LTSB

    DCPHK-NFMTC-H88MJ-PFHPY-QJ4BJ

    Windows 10 Enterprise 2016 LTSB N

    QFFDN-GRT3P-VKWWX-X7T3R-8B639

    Product keys for Windows 10 Version Update 2021

    During installation, Windows ten can raise you for a product activation key. you may not be able to plow ahead any while not getting into a sound key. If you wish to check Windows or install Windows while not getting into your purchased license key, you’ll simply use the subsequent generic Windows ten activation product keys which can allow you to success install Windows with thirty days ending. you’ll extend the ending up to ninety days.

    Windows 10 Enterprise Evaluation

    MNXKQ-WY2CT-JWBJ2-T68TQ-YBH2V

    Windows 10 Enterprise

    XGVPP-NMH47-7TTHJ-W3FW7-8HV2C

    Windows 10 Professional Workstation

    WYPNQ-8C467-V2W6J-TX4WX-WT2RQ

    Windows 10 Education

    84NGF-MHBT6-FXBX8-QWJK7-DRR8H

    Windows 10 Professional

    VK7JG-NPHTM-C97JM-9MPGT-3V66T

    Windows 10 Activation Key Full Working

    XGVPP-NMH47-7TTHJ-W3FW7-8HV2C

    NPPR9-FWDCX-D2C8J-H872K-2YT43

    Professional Work Station

    WYPNQ-8C467-V2W6J-TX4WX-WT2RQ

    NX6TT-WH4BH-CJC2P-M98B8-33YPV
    Education 

    84NGF-MHBT6-FXBX8-QWJK7-DRR8H

    Starter

    D6RD9-D4N8T-RT9QX-YW6YT-FCWWJ
    professional

    VK7JG-NPHTM-C97JM-9MPGT-3V66T
    professional

    2B87N-8KFHP-DKV6R-Y2C8J-PKCKT
    Enterprise 

    XGVPP-NMH47-7TTHJ-W3FW7-8HV2C
    Education

    YNMGQ-8RYV3-4PGQ3-C8XTP-7CFBY

    Server Storage Standard Core

    9JFKN-MWC8F-X8PVJ-RG34X-9HD27
    Enterprises

    2D7NQ-3MDXF-9WTDT-X9CCP-CKD8V
    Server Data Center Nano

    BFM6D-TKNBY-X6RGR-PHJ4G-723B6

    Windows 10 Product Key All Edition Updated 2021

    Windows 10 Home Edition – YTMG3-N6DKC-DKB77-7M9GH-8HVX7

    Windows 10 Single Language Key – BT79Q-G7N6G-PGBYW-4YWX6-6F4BT

    Windows 10 Pro Serial Key– VK7JG-NPHTM-C97JM-9MPGT-3V66T

    Windows 10 Enterprise Product Key Updated 2021

    NPPR9-FWDCX-D2C8J-H872K-2YT43

    PBHCJ-Q2NYD-2PX34-T2TD6-233PK

    Windows 10 Product Code and Serial Key:

    Windows 10 Serial Key:
    NPPR9-FWDCX-D2C8J-H872K-2YT43

    Windows 10 OS key Professional Edition:
    6P99N-YF42M-TPGBG-9VMJP-YKHCF
    8N67H-M3CY9-QT7C4-2TR7M-TXYCV
    Windows 10 product key: Technical Preview for Consumer:
    334NH-RXG76-64THK-C7CKG-D3VPT

    Windows 10 Product key all Editions:
    NKJFK-GPHP7-G8C3J-P6JXR-HQRJR

    Windows 10 key Enterprise Edition:
    CKFK9-QNGF2-D34FM-99QX2-8XC4K

    Windows 10 product number:
    VK7JG-NPHTM-C97JM-9MPGT-3V66T

    W269N-WFGWX-YVC9B-4J6C9-T83GX

    T44CG-JDJH7-VJ2WF-DY4X9-HCFC6

    How to activate Windows 10 without product key for free 2021 (180 days)

    KMS client setup keys

    • Readout Article First HERE

    Step 1: You select the right key for the Windows 10 edition you use.
    Here is the list of Windows 10 KMS keys:

    • Windows 10 Pro key: W269N-WFGWX-YVC9B-4J6C9-T83GX
      Windows 10 Pro N key: MH37W-N47XK-V7XM9-C7227-GCQG9
    • Windows 10 Pro Workstations key: NRG8B-VKK3Q-CXVCJ-9G2XF-6Q84J
    • Windows 10 Pro Workstations N key: 9FNHH-K3HBT-3W4TD-6383H-6XYWF
    • Windows 10 Pro Education key: 6TP4R-GNPTD-KYYHQ-7B7DP-J447Y
    • Windows 10 Home key: TX9XD-98N7V-6WMQ6-BX7FG-H8Q99
    • Windows 10 Home N key: 3KHY7-WNT83-DGQKR-F7HPR-844BM
    • Windows 10 HomeHome Single Language key: 7HNRX-D7KGG-3K4RQ-4WPJ4-YTDFH
    • Windows 10 Home Country Specific: PVMJN-6DFY6-9CCP6-7BKTT-D3WVR
    • Windows 10 Education key: NW6C2-QMPVW-D7KKK-3GKT6-VCFB2
    • Windows 10 EducationN: 2WH4N-8QGBV-H22JP-CT43Q-MDWWJ
    • Windows 10Enterprise key: NPPR9-FWDCX-D2C8J-H872K-2YT43
    • Windows 10Enterprise N key: DPH2V-TTNVB-4X9Q3-TJR4H-KHJW4
    • Windows 10 Enterprise G: YYVX9-NTFWV-6MDM3-9PT4T-4M68B
    • Windows 10 Enterprise G N: 44RPN-FTY23-9VTTB-MP9BX-T84FV
    • Windows 10Enterprise LTSC 2019 key: M7XTQ-FN8P6-TTKYV-9D4CC-J462D
    • Windows 10Enterprise N LTSC 2019 key: 92NFX-8DJQP-P6BBQ-THF9C-7CG2H
    • Windows Enterprise LTSB 2016 key: DCPHK-NFMTC-H88MJ-PFHPY-QJ4BJ
    • Windows Enterprise N LTSB 2016 key: QFFDN-GRT3P-VKWWX-X7T3R-8B639
    • Windows 10 Core: 33QT6-RCNYF-DXB4F-DGP7B-7MHX9
    • Windows 10 S (Lean): NBTWJ-3DR69-3C4V8-C26MC-GQ9M6

    Step 2: You right-click on the start button and open Command Prompt (Run as Administrator)

     

    Step 3: You use the command “slmgr.vbs /ipk yourlicensekey” to install a license key (yourlicensekey is the activation key you got at step 1).

     

    For example, my Windows 10 is Windows 10 Pro. So I type:
    slmgr.vbs /ipk W269N-WFGWX-YVC9B-4J6C9-T83GX

    (*Note*: You need to hit [Enter] key to execute commands.)

    Step 4: You use the command “slmgr.vbs /skms kms8.msguides.com” to connect to my KMS server.

     

    Zoom Player Max Keygen height="148">

    Step 5: The last step you use the command “slmgr.vbs /ato”.

     

    You check the activation status again.

    If these keys don’t work, you can find a new method in this article. I tested on 5-15-2021.

    Step 1: You visit Windows10txt
    Step 2: Copy the code above into a new text document

    Step 3: Save it as a batch file, name “1click.cmd”

    Step 4 : Run the batch file as administrator

    You can see the result

    So, Please feedback must in the comment if my windows 10 Product keys not working our 2nd method not working then write a comment am provide you latest working keys our solve your problem for windows activation I hope you like my article our helpful for you am more thing daily bases added more software keys.

    This Video is more Help to Activate Your Windows I hope am Daily updated keys and Reply On Comments 

    In this video, I will show you a very simple and quick way to activate windows 10 pro 64 bit for …

    slmgr.vbs /ipk W269N-WFGWX-YVC9B-4J6C9-T83GX

    slmgr.vbs /skms kms.lotro.cc

    slmgr.vbs /ato

    Windows 10 Professional N Product Key:

    MH37W-N47XK-V7XM9-C7227-GCQG9

    Источник: https://iproductkeys.com/windows-10-product-key-2019/
    Back to All Events
    sunroom-tests-2.jpg

    Introducing the Sun Room
    Realm’s new Studio

    Located in what was formerly, the cafe, the Sun Room has been thoughtfully reinvented to better serve both Studio and Event activation at Realm. This new Studio features its own Cyc Wall, Movable wall, Movable bar and will continue to feature Realm’s signature blush banquette.

     

    + Highlighting New Features
    in the Open Space and the Loft

    The Open Space has also acquired its very own Movable wall, and a few new pieces that will be introduced throughout the next few months, giving Realm clients new silhouettes and aesthetics to play up. The Loft (formerly the Mezzanine) was also reinvented as a green room, featuring lounge furniture as well as a Hair & Makeup station.

     

    5L1A8117.jpg

    Win a FREE 2 Hour Booking
    in the New Sun Room

    All you have to do is attend the open house and you’ll be entered to win. There will be multiple winners so be sure to drop by, and toss your name into the ring.

     

    Bring Your Cameras

    Consider this your excuse to get dressed up on a Saturday night. With all these new features, surely you’ll want to try them out while you’re here?

     

    exterior-1.jpg

    Directions

    The Easy Way

    • Open Google or Apple Maps

    • Type in Realm Denver

    • Get Directed to Our Corner of the Building

    The Hard Way

    Источник: https://www.realmdenver.co/hosted-events/open-house-2021

    It is our commitment to you that you are comfortable with your investment. In light of these uncertain times, the Pirates are pledging to provide assurance to you that your investment in Pirates Baseball will be guaranteed.

    HEALTH AND SAFETY

    The Pirates are committed to implementing health and safety protocols to help minimize risk and maximize your experience at PNC Park. We will be taking the necessary steps and are focused on providing the highest-quality safety measures before, during, and after each game. To help create a safe experience at PNC Park, we are committed to, at minimum, implementing and adhering to the recommendations and guidelines set forth by public health officials.

    SEAT PROTECTION

    In the event your 2021 seats are impacted due to restricted capacity or a reduced number of regular season home games resulting from the pandemic, we will do everything possible to provide you the best seat location and season ticket plan that meets your expectation. If we are unable to meet that expectation, you will have the opportunity to use the money on your account towards a different ticket purchase in 2021, a credit for the 2022 season or a refund back to your initial payment method. In the event 2021 home games require reduced seating capacity, Pirates season ticket holders will be guaranteed seating opportunities before the general public.

    OTHER UPDATES

    We will continue to provide updates via email when we have any additional information. Please feel free to contact us at 1-800-BUY-BUCS (1-800-289-2827) or via email at [email protected].

    Источник: https://www.mlb.com/pirates/tickets/2021-ticket-information-waitlist
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Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation

Abstract

A regioselective carbosilylation of alkenes has emerged as a powerful strategy to access molecules with functionalized silylated alkanes, by incorporating silyl and carbon groups across an alkene double bond. However, to the best of our knowledge, organic June 12 have never been used in this protocol. Here we disclose the catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides mediated by tBuOK. The main feature of this transformation is the selective activation of the C-F bond of an organic fluoride by the silyl boronate without undergoing potential side-reactions involving C-O, C-Cl, heteroaryl-CH, and even CF3 groups. Various silylated alkanes with tertiary or quaternary carbon centers that have aromatic, hetero-aromatic, and/or aliphatic groups at the β-position are synthesized in a single step from substituted or non-substituted aryl alkenes. An intramolecular variant of this carbosilylation is also achieved via the reaction of a fluoroarene with a ω-alkenyl side chain and a silyl boronate.

Introduction

The use of two independent reactants for the transition-metal-catalyzed difunctionalization of alkenes has emerged as a powerful strategy to access molecules with multiple functional groups, by incorporating two new functional groups across an alkene double bond1,2,3,4,5,6. One of the two coupling partners commonly used in this context are activated halogenated arenes or alkanes, or an equivalent thereof (Ar-X or Alkyl-X; X = e.g., I, Br, Cl, OTf, or OMs). Reactions using these molecules generally proceed via oxidative addition and/or radical processes7,8,9,10,11,12,13,14,15. In contrast, fluorinated compounds such as aryl or alkyl fluorides have not yet been used as a counterpart for the difunctionalization of alkenes due to the high bond-dissociation energy of the carbon–fluorine (C–F) bond (Fig. 1a).

a General figure for the difunctionalization of alkenes. b Carbosilylation of alkenes with silyl boronates and organic fluorides.

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In recent years, a variety of organofluorine compounds has become ubiquitous due to the rapid establishment of technologies for their synthesis16,17,18. There are more than 340 registered fluoro-pharmaceuticals19 with complex structures and more than 425 registered fluoro-agrochemicals20. It has been estimated that there are more than 8,800,000 commercially available fluoroarenes (SciFinder®). Thus, the functionalization of organic fluorides via the cleavage/activation of C–F bonds in organic fluorides is a dynamic and emerging area of research that will expand the utility of organofluorine molecules21,22,23,24. However, the chemical transformation of fluoro-organic compounds via C–F bond cleavage under very mild conditions is still rare. For example, aryl fluorides have rarely been functionalized due to the difficulty of oxidative addition of low-valent transition metals to C(sp2)-F bonds, whereas the field of C(sp2)-F cleavage using silyl cooperativity and/or transition-metal catalysis has also benefited from a wide breadth of research, especially in the last decade24,25,26,27,28,29,30. Activation of C(sp3)-F bonds in aliphatic fluorocarbons is mostly limited to reactive benzyl or allylic fluorides where p-block-based Lewis acids with high fluoride affinity are usually required31,32,33. Thus, the activation of inert C–F bonds in aromatic and aliphatic organic fluorides under mild conditions remains highly challenging.

To realize the difunctionalization of alkenes using organic fluorides as one of the coupling partners, we decided to investigate the carbosilylation of alkenes34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49. This reaction provides functionalized organosilicon compounds directly from simple alkenes, compounds that are much sought-after materials in organic synthesis50,51, electronics52,53, photonics54, and drug discovery55. Despite previous successes in the hydrosilylation of alkenes56,57, research on the carbosilylation of alkenes is still in its infancy34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49. One of the early milestones in this area is the work by Terao and colleagues37. They disclosed a titanocene-catalyzed carbosilylation of alkenes using alkyl bromides and chlorides with chlorosilanes mediated by the Grignard reagent. For recent examples, Engle and colleagues42 reported a Pd-catalyzed arylsilylation of alkenes using dimethylphenyl silyl boronate PhMe2SiBPin and aryl triflates. Zhang and Hu49 demonstrated an arylsilylation of acrylates with tri(trimethylsilyl)silane and aryl bromides using a nickel/photoredox catalyst. Although several achievements have been reported in carbosilylation reactions of alkenes under metal-catalyzed and photo-induced conditions, the present methods are still limited by the substrate scope. Besides, the aryl and alkyl fluorides have never been used for the three-component carbosilylation of alkenes. Our group has been engaged in the development of efficient methods for the selective functionalization of C(sp2)-F and C(sp3)-F bonds under mild conditions both with58 or without58,59,60,61 the use of transition metals. In this context, our recent report on the defluorosilylation of organic fluorides using silyl boronates and with or without a Ni catalyst58 inspired us to undertake a much more challenging research topic: the difunctionalization of alkenes with aryl or alkyl fluorides in the presence of silyl boronates via C–F bond cleavage (Fig. 1b).

Herein, we disclose a protocol consisting of the catalyst-free defluorinative carbosilylation of alkenes with silyl boronates and fluorinated compounds with an inert C(sp3)-F or C(sp2)-F bond. A wide variety of aryl fluorides and alkyl fluorides are smoothly incorporated into the alkenes via the cleavage of a C–F bond in the presence of silyl boronates to provide β-functionalized silyl alkanes in good to excellent yield, without any help of transition-metal catalysis nor photoredox system. The alkene, aryl fluoride, 360 total security full version with crack download - Crack Key For U alkyl fluoride substrate scope tolerated by this reaction is extensive. Unsubstituted styrene derivatives as well as substituted and conjugated aryl alkenes react smoothly with a great variety of aryl or alkyl fluorides and silyl boronates. This allows access to a library of silyl compounds that regioselectively incorporate aryl, heteroaryl, and/or alkyl units at the β-carbon of the silyl alkanes. The reaction proceeds with high regio- and chemoselectivity. Aryl and conjugated alkenes are reactive, whereas non-aryl alkenes are entirely unreactive. The potentially cleavable C-O bond of ethers62, C-Cl bonds63, and the C(sp2)-H bond of hetero-aromatic compounds64,65 are well-tolerated. Most significantly, the C(sp3)-F bond of the EZ CD Audio Converter 9.5.0.1 Crack With License Key Free Download (CF3) group66 remains intact. An intramolecular carbosilylation via the cleavage and coupling of a C–F bond was also achieved. Three-component coupling reactions involving drug derivatives that contain a fluoride moiety were also demonstrated to prove the utility of this transformation in the drug discovery process. The reaction should proceed through a cascade radical process initiated by single-electron transfer, which was supported by the experimental studies.

Results and discussion

Optimization of the reaction conditions

We first investigated the reaction of 4-fluorobiphenyl (1a) with styrene (3a) in the presence of the silyl boronate Et3SiBpin and a variety of catalysts (Table 1, also see Supplementary Tables S1–S5 for more details). Using the conditions described in our earlier report58 on the defluorosilylation of aryl fluorides [Et3SiBpin (1.5 equiv), Ni(COD)2 (10 mol%), and potassium tert-butoxide (KOtBu, 2.5 equiv) in cyclohexane/tetrahydrofuran (THF) at room temperature], the expected biphenyl-phenylethyl-triethylsilane 4aa was obtained regioselectively in 32% yield (entry 1, Table 1). Encouraged by this initial attempt, the optimum amount of base required was explored and 4.0 equiv of KOtBu was found to be the most suitable quantity (entries 1–3). We next varied the equivalents of Et3SiBpin used and found that 2.0 equiv was the optimum amount (entry 4). After slight modifications to the solvent ratios, including testing a single solvent, the binary solvent cyclohexane/THF (8/1, v/v) was found to be most suitable (entry 5). Notably, reducing the Ni(COD)2 catalyst loading to 1 mol% afforded 4aa in 99% yield, which is similar to that obtained in entry 5, within 2.5 h without eroding the reaction efficiency (entry 6). Replacement of KOtBu with NaOtBu resulted in the formation of 4aa in merely 15% yield (entry 7). In the absence of a base or when using other bases (LiOtBu, KOMe, or KHMDS), the desired product was not obtained (entries 8 and 9). Moreover, a large excess of 3a had a negative effect on the reaction yield (entry 10). To ascertain the effect of Ni(COD)2, we finally examined the reaction without Ni catalyst. We were very supersized that the transformation occurred efficiently even in the absence of Ni(COD)2 to generate 4aa in 94% yield (91% isolated yield, entry 11). The results are almost identical to the reaction with Ni catalysis (entry 6). We thus decided the further examination using the different substrates under the two type conditions, with or without Ni(COD)2.

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Substrate scope

With the optimized reaction conditions (Table 1, entries 6 and 11), we investigated the scope of the Ni-catalyzed or catalyst-free carbosilylation of the alkenes 3 with fluoroarenes 1 and Et3SiBpin (Fig. 2). First, the scope of the aromatic fluorides was examined under catalyst-free conditions (entry 11, Table 1). A wide range of fluoroarenes that bear π-extended building blocks were efficiently converted into the corresponding defluorinative arylsilylation products (4) in good to high yield. For example, biphenyl products (4aa: 91%; 4ba: 87%; 4ca: 42%), a 1-naphthyl product (4da: 87%), and 4-(naphthalen-1-yl)phenyl (4ea: 90%) were all obtained using this methodology. Simple fluorobenzene (1f) was also efficiently converted into arylsilylation product 4fa (63%), whereas 4-methyl-substituted aryl fluoride 1g provided a higher yield (4ga: 85%). The excellent chemoselectivity profile of this process is nicely illustrated by the tolerance of the reaction conditions toward functional groups such as ethers (-O-: 1h, 1i, and 1j), CF3 groups (1k and 1l), or Cl groups (1m), all of which could potentially be cleaved with the C–F bond activation. The desired products 4 were obtained in the following yields: 4ha: 75%, 4ia: 73%, 4ja: 69%, 4ka: 50%, 4la: 53%, 4ma: 70%. It was most surprising to find that the CF3 groups of 1k and 1l remained intact. We next repeated the same substrate scope by the best reaction conditions in the presence of Ni(COD)2 (entry 6, Table 1). Although the June 12 products 4aa4na were somewhat improved, the differences were not so significant, as shown in Fig. 2.

aThe reaction was carried using 1 or 2 (0.2 mmol), 3 (2.0 equiv.), Et3SiBpin, Me2PhSiBpin, nPr3SiBpin or tBuMe2SiBpin (2.0 equiv.), and KOtBu (4.0 equiv.) in cyclohexane/THF (1.5 mL, 8/1, v/v) at room temperature. bIsolated yield is shown. cThe reaction was carried out in the presence of Ni(COD)2 (1.0 mol%). d0.4 mmol of 1 was used.

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Encouraged by the fact that the transformation fundamentally does not require Ni catalyst, we continued the substrate scope under catalyst-free conditions (entry 11, Table 1). Next, we focused on the hetero-aromatic fluorides 1n1u. The nitrogen-containing hetero-aromatic fluorides 1n1t were successfully coupled with 3a in the presence of Et3SiBpin in good to high yield; a 1H-indole derivative (4na: 57%), 1H-pyrrole derivative (4oa: 32%), and a number of pyridine derivatives (4pa: 80%; 4qa: 68%; 4ra: 74%; 4sa: 88%) were well-tolerated under the optimized conditions. Fluoro-indole (1t) and fluoro-benzofuran (1u), despite having several reactive aryl C(sp2)–H bonds, also participated well in this transformation, selectively furnishing carbosilylation products 4ta (85%) and 4ua (49%) via C–F bond cleavage, without the anticipated C–H activation–silylation reaction of the hetero-aromatic moiety. Notably, other silyl boronates such as PhMe2SiBpin, nPr3SiBPin, and tBuMe2SiBPin, could also be used in this transformation instead of Et3SiBpin. The corresponding silylated products 4aa’, 4aa”, and 4aa”' were obtained from fluoroarene 1a and styrene (3a) in 47%, 88%, and 94% yields, respectively.

Next, we set out to evaluate the scope of the alkene component (3) of the reaction. A range of aryl alkenes were efficiently converted into the corresponding arylsilylation products 4 in the presence of aryl fluoride 1 and Et3SiBpin. 2-Vinylnaphthalene 3b, a simple polycyclic aromatic compound, successfully reacted with 1a to afford the corresponding arylsilylation product (4ab, 58%). Styrene derivatives bearing Me (3c), tBu (3d), phenyl (3e), MeO (3f, 3g), dioxole (3h), and MeS (3i) groups were all, even the highly sterically hindered ortho-MeO-styrene 3g, well-tolerated as substrates and furnished the desired products 4 in good to excellent yield (4ac: 81%; 4ad: 67%; 4ae: 79%; 4af: 81%; 4ag: 75%; 4ah: 59%, 4ai: 91%). It is important to note that this three-component coupling reaction tolerated any combination of the coupling components. A wide variety of substituted or non-substituted fluoroarenes 1, aryl alkenes 3, and silyl boronates R3SiBpin furnished the desired silylated alkanes 4 in good to high yield (4cg: 46%; 4ci: 33%; 4lc: 70%; 4mc: 84%; 4vi: 65%; 4ab’: 92%). We also investigated the reaction of substituted styrene derivatives with a quaternary carbon center at the β-position of the silyl moiety. For example, α,α-diphenylethylene 3j, α-methylstyrene 3k, and (4-methoxybut-1-en-2-yl)benzene 3l reacted with fluoroarenes 1 under the standard reaction conditions to give the corresponding products 4 (4aj: 71%; 4ak: 90%; 4al: 51%; 4fk: 73%; 4mk: 69%). Furthermore, we attempted the defluorinative alkylsilylation of alkenes using alkyl fluorides with an inert C(sp3)–F bond under the same reaction conditions. Primary alkyl fluorides 2a2h efficiently reacted regioselectively with styrenes (3a, 3c, 3i) to afford the corresponding alkylsilylation products in up to 94% yield (5aa: 94%; 5ba: 89%; 5ca: 85%; 5da: 91%; 5ei: 76%; 5fi: 86%; 5gi; 40%; 5hc: 83%). Notably, the trifluoromethoxy (CF3O) moiety of 2d remained intact to provide 5da. Secondary alkyl fluorides 2i and 2j also furnished the desired defluorinative alkylsilylation products 5ia and 5ja in 36% and 52% yield, respectively. The reaction using alkyl fluorides was also carried out in the presence of Ni(COD)2 catalyst (1 mol%) under the best conditions 360 total security review - Crack Key For U 6, Table 1). We obtained almost the same results (72–95%) as the yields without Ni catalyst. Thus, the defluorinative carbosilylation does not require Ni catalysis independent of the case of aryl or alkyl fluorides.

To highlight the synthetic utility of this three-component defluorinative carbosilylation reaction, we examined the functionalization of several drug derivatives with fluoroarene moieties (Fig. 3). (±)-α-Tocopherol derivative 1w successfully underwent carbosilylation to afford (±)-α-tocopherol derivative 4wa in 43% yield (Fig. 3a). (-)-Menthol-derived fluorobenzene 1x proceeded well under identical conditions to give carbosilylation product 4xa in 55% yield (Fig. 3b). Steroid derivatives 4ya and 4am were June 12 in 53% and 79% yield via (1) the defluorination of fluoro-incorporated estrone derivative 1y or (2) the defluorination of 1a with alkene- incorporated estrone derivative 3m (Fig. 3c, d). Moreover, the liquid crystalline material 1z was also successfully functionalized using this transformation with 3i to give XLStat Offline Installer in 41% yield (Fig. 3e).

a (±)-α-Tocopherol derivative. b Menthol derivative. c, d Estrone derivatives. e Liquid crystalline material derivative.

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Furthermore, we examined both the chemoselectivity and site-selectivity of the alkenyl moiety (Fig. 4). (E)-Buta-1,3-dien-1-ylbenzene (3n) was site-selectively converted into the 1,4-type arylsilylation product 4an in 41% yield with an E/Z ratio of 1.1/1 (determined by 1H nuclear magnetic resonance (NMR) analysis), whereas no 1,2-adduct was observed (Fig. 4a). Conversely, phenoprene 3o preferably furnished 4ao (65%), a compound with a quaternary carbon center, under the standard reaction conditions via the 1,2-arylsilylation process and not the 1,4-process (Fig. 4b). When we examined the reaction of 1-(but-3-en-1-yl)-2-fluorobenzene (6a) with 3a in the presence of Et3SiBpin, only the three-component condensation product 7aa was obtained in 51% yield, whereas the intramolecular product was not detected (Fig. 4c). For the reaction of 6-fluorohex-1-ene (2k) and 10-fluorodec-1-ene (2l) having a terminal olefin moiety with styrenes 3a and 3i, the three-component condensation products 5ka and 5li were obtained in 93% and 70% yields, respectively, whereas the intramolecular products were not detected (Fig. 4d, e). In contrast, an intramolecular carbosilylation was achieved via the reaction of styrene-substituted fluoroarene 6b6d with Et3SiBpin under identical conditions to furnish 8b8d, molecules with a quaternary carbon center, in 81–95% yield (Fig. 4f–h). The five-component condensation was observed for the reaction of di-functionalized 1,8-difluorooctane (2m) with styrene 3c and Et3SiBpin to provide 5mc in 88% yield (Fig. 4i). It should be noted that, under the applied conditions, bromo- and iodo-substituted arenes 9, 10 afforded a mixture of two-component condensation products of silylated 11 and borylated 12 compounds, whereas the targeted three two-component product 4aa was not detected (Fig. 4j). We also attempted the reaction of alkyl chloride 13 instead of alkyl fluoride 3a under the same Mixcraft Pro Studio 9.0 Build 469 Registartion Code Crack. Although the three-component product 5aa was obtained by alkyl fluoride 3a, the two-component product, triethyl(phenethyl)silane (14), made from 3a and Et3SiBPin, was obtained in 22% yield without incorporation of alkyl chloride 13 (Fig. 4k). Alkyl bromide and iodide were also not converted into 5aa under identical conditions (Supplementary Fig. 5). Encouraged by the results, we attempted the chemoselective activation of the alkyl C–F bond over the alkyl C–Cl bond by the competitive reaction between 2a and 13. Interestingly, the alkyl fluoride 2a was consumed to 5aa (95%), whereas the alkyl chloride 13 was recovered (90%, Fig. 4l, more details in Supplementary Figs. 6–8). These behaviors show the advantage of fluorine in our reaction system compared to commonly used halogens both in aromatic and aliphatic cases.

a Selective 1,4-type addition carbosilylation of 1,3-diene 3n. b Selective 1,2-carbosilylation of 1,3-diene 3o. ce Selective three-component carbosilylation of styrenes (3a or 3i) in the presence of an aliphatic alkene moiety in aryl fluoride 6a or alkyl fluorides 2k, or 2l. fh Intramolecular carbosilylation of 6bd to provide cyclized silylated products 8bd. i Five-component carbosilylation of styrene 3c with 1,8-difluorooctane (2m). j Comparisons of aryl halides (1a, 9, and 10) for the carbosilylation. k Comparisons of alkyl halides (2a and 13) for the carbosilylation. l The competitive reaction between 2a and 13.

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Mechanistic study

Based on this consideration and on the results obtained so far, a radical pathway seems to be a viable hypothesis. To gain an insight into the reaction mechanism, some experiments were undertaken. First the transformation of 1a with 3a to 4aa under the best conditions was significantly inhibited by the addition of (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) (Fig. 5a). These results strongly suggested the reaction involves radical species. We also attempted the same reaction in the presence of Ni catalyst. The same results were obtained. We next examined the radical clock experiment with the substrate containing a cyclopropyl moiety at the α-position of the styrene derivative 3p (Fig. 5b). The silylated ring-opening product 15 was obtained as a major product in 55% yield and most of the aryl fluoride 1a was recovered. On the other hand, the expected three-component product was not clearly observed, the trace of the desired material was detected only by gas chromatography–mass spectrometry (GCMS). The results are also in good agreement with the radical-mediated reaction mechanism, as the potential cyclopropyl carbinyl radical is known to spontaneously rearrange to allylcarbinyl radical. Furthermore, the substrate 6e having both fluoroarene and styrene moieties was transformed into the silyl-cyclopropyl compound 16 in 76% yield (Fig. 5c), which also supports the radical pathway. The treatment of 2k with Et3SiBPin in the absence of styrenes 3 predominantly gave a silylalkene 17 in 73% yield via C–F bond activation, whereas the transformation was completely inhibited by the addition of TEMPO independent of the existence of Ni catalyst (Fig. 5d). Thus, the generation of radical species does not require the reaction with styrenes 3.

a Effect of TEMPO for carbosilylation of 1a, 3a, and Et3SiBPin. b, c Radical clock experiments. d Effect of TEMPO for the reaction of alkyl fluoride 2k and Et3SiBPin. e Proposed reaction mechanisms.

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Based on both the experiments’ results here and in previous reports44,67,68,69,70,71,72,73,74, we propose a single-electron transfer/radical-mediated carbosilylation reaction mechanism triggered by the known ability of KOtBu to serve as a single-electron reductant75,76 (Fig. 5e). First, Et3SiBpin reacts with a molecule of KOtBu to form an intermediate A. The formation of A has previously been confirmed by the Avasare group based on density functional theory calculations77. We also confirmed the intermediate A by the 11B-NMR and 29Si-NMR study (Supplementary Figs. 12–15)58. Next, a single-electron transfer process would start by the additional amount of KOtBu as a trigger75,76. Namely, a single electron is transferred from t-butoxy anion (OtBu) to the silicon atom of intermediate A to furnish a triethylsilyl radical ˙SiEt3 via a cleavage of the Si–B bond. The t-butoxy radical ˙OtBu is also generated, which would be captured by the borate anion B. The mechanisms for the cleavage of Si–B bonds are various; the radical-mediated Si–B bond cleavage78,79,80 should be highly acceptable due to the experimental results using tBuOK75,76. The generated triethylsilyl radical ˙SiEt3 reacts with styrene 3a to give a radical adduct C. The radical cascade process should happen between the radical species C, aryl 1 or alkyl fluorides 2, t-butoxy radical ˙OtBu, and borate anion B in the transition state TS-I, where the C–F bond of aryl 1 or alkyl fluorides 2 is activated by the approach of K+. The boron atom in B would also participate in activation of the C–F bond. Finally, the C–C bond formation is completed under concomitant generation of stable D [BPin(OtBu)2]K (Supplementary Fig. 14)58 and KF to furnish the desired three-component adduct 4 or 5. The generation of benzyl radical species C was supported by the cyclopropyl experiments (Fig. 5b, c). It should be noted that through the experiments, we observed side products such as Et3Si-SiEt3 and double styrene adducts 18. These formations can be explained by the dimerization of triethylsilyl radical ˙SiEt3 and the overreaction of benzyl radical C with styrene 3a.

In conclusion, we have developed a carbosilylation of alkenes that uses silyl boronates and organic fluorides, and that proceeds via the activation of an inert C–F bond without a catalyst. This reaction should be initiated by the radical cleavage of Si–B bond via a single-electron transfer from tBuOK. A variety of β-functionalized silyl compounds can be synthesized efficiently and rapidly in good to excellent yield under very mild conditions at room temperature. The most significant feature of this protocol is its broad substrate scope. This highly efficient protocol accepts a variety of fluorides, including aryl and alkyl fluorides, and even transforms sterically demanding secondary alkyl fluorides. A broad range of aryl alkenes, such as styrene derivatives and α-substituted aryl alkenes, are also tolerated by this method. Silyl boronates were identified as viable substrates. Moreover, the chemo- and site-selectivity displayed in this reaction are remarkable. Aryl alkenes selectively react in the presence of non-aryl alkenes and an intramolecular carbosilylation was achieved with substrates that possess both fluoroarene and aryl alkene moieties. The tolerance of the reaction toward different functional groups is also significant. Substrates with ether, CF3, and hetero-aromatic moieties react smoothly without the detection of C–O cleavage, C–F bond activation, or C–H activation; only the inert C–F bonds of the fluoroarenes and fluoroalkanes are activated. Notably, this method also allows for the synthesis of silyl compounds with a quaternary carbon center at the β-position. The 1,4-type addition carbosilylation of 1,3-dienes was also achieved. Given the high number of fluorinated compounds that are commercially available, including structurally complex pharmaceuticals, agrochemicals, and functional materials, this protocol widens the potential utility of organosilicon compounds in organic synthesis, the structural design of lead drug compounds, and functional materials.

Finally, the limitations of the method should be mentioned. The conjugated diene is acceptable but electron-deficient acrylates and acrylamides are not suitable. Internal styrenes such as cis-stilbene and trans-β-methylstyrene did not react (Supplementary Figs. 1 and 2). The chemoselective activation of aromatic C–F bonds over aromatic C–Br and C–I bonds is difficult, whereas the only aromatic fluoride was transformed into the desired three-component product (Supplementary Figs. 3 and 4).

Methods

General procedure for the defluorinative carbosilylation of alkenes 3 using R3SiBpin and aryl fluorides 1 or alkyl fluorides 2

In a N2-filled glovebox to a flame-dried screw-capped test tube were added organic fluorides 1 or 2 (0.20 mmol, 1.0 equiv), silyl boronates R3SiBpin (0.4 mmol, 2.0 equiv), alkenes 3 (0.40 mmol, 2.0 equiv), KOtBu (90 mg, 0.8 mmol, 4.0 equiv), and cyclohexane/THF (1.5 mL, 8/1, v/v) sequentially. The tube was then sealed and removed from the glovebox. The mixture was stirred at room temperature for 2.5 h. To the reaction tube was added hexane (5 mL) and then it was subjected to filter through a short silica pad, washed with Et2O, and concentrated under vacuum, followed by 3-fluoropyridine (8.6 μL, 0.1 mmol) as an internal standard for NMR analysis. The mixture was then concentrated again to give the residue, which was purified by column chromatography on silica gel to give the corresponding carbosilylation products 4 or 5.

Data availability

The data supporting the findings of this study are available within the paper and its Supplementary Information. All relevant data are also available from the authors.

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Источник: https://www.nature.com/articles/s41467-021-24031-w

Windows 11

Personal computer operating system by Microsoft released in 2021

Windows 11 logo.svg
Windows 11 Desktop.png

Screenshot of Windows 11, showing the new Start menu and centered taskbar[1]

DeveloperMicrosoft
Written in
OS familyMicrosoft Windows
Source model
Released to
manufacturing
October 5, 2021; 46 days ago (2021-10-05)
General
availability
October 5, 2021; 46 days ago (2021-10-05)[6]
Latest release21H2 (10.0.22000.318) (November 9, 2021; 11 days ago (2021-11-09)[7]) [±]
Latest preview10.0.22504.1010 (November 19, 2021; 1 day ago (2021-11-19)[8]) [±]
Marketing targetPersonal computing, tablets
Available in110 languages[9][10]

List of languages

Update method
Platformsx86-64, ARM64
Kernel typeHybrid (Windows NT kernel)
UserlandNative API
Windows API
.NET Framework
Universal Windows Platform
Windows Subsystem for Linux
Default
user interface
Windows shell (graphical)
Preceded byWindows 10 (2015)
Official websitewww.microsoft.com/windows/windows-11Edit this at Wikidata
See § Versions for details.

Windows 11 is a major release of the Windows NToperating system developed by Microsoft that was announced on June 24, 2021, and is the successor to Windows 10, which was released in 2015. Windows 11 was released to the public on October 5, 2021, as a free upgrade via Windows Update and Windows 11 Installation Assistant on eligible devices running Windows 10.

Windows 11 features major changes to the Windows shell influenced by the canceled Windows 10X, including a redesigned Start menu, the replacement of its "live tiles" with a separate "Widgets" panel on the taskbar, the ability to create tiled sets of windows that can be minimized and restored from the taskbar as a group, and new gaming technologies inherited from Xbox Series X and Series S such as Auto HDR and DirectStorage on compatible hardware. Internet Explorer (IE) has been replaced by the Chromium-based Microsoft Edge as the default web browser (for compatibility[11][12] with Google Chrome web browser[13]), and Microsoft Teams is integrated into the Windows shell. Microsoft also announced plans to allow more flexibility in software that can be distributed via Microsoft Store, and to support Androidapps on Windows 11 (including a partnership with Amazon to make its app store available for the function.

Citing security considerations, the system requirements for Windows 11 were increased over Windows 10. Microsoft only officially supports the operating system on devices using an eighth-generationIntel Core CPU or newer (with some exceptions), AMD Ryzen CPU based on Zen+ microarchitecture or newer, or a Qualcomm Snapdragon 850ARMsystem-on-chip or newer, with UEFI secure boot and Trusted Platform Module (TPM) 2.0 supported and enabled (although Microsoft may provide exceptions to the TPM 2.0 requirement for OEMs). While the OS can be installed on unsupported processors, Microsoft does not guarantee the availability of updates. Windows 11 also drops support for 32-bitx86 CPUs and devices which use BIOS firmware.

Windows 11 has received a mixed to positive reception; pre-release coverage of the operating system focused on its stricter hardware requirements, with discussions over whether they were legitimately intended to improve the security of Windows or a ploy to upsell users to newer devices, and over e-waste associated with the changes. Upon its release, Windows 11 received positive reviews Any Video Converter Ultimate 6.2.4 Crack Full License Key Download its improved visual design, window management, and stronger focus on security, but was panned for regressions and modifications to aspects of its user interface.

Development

At the 2015 Ignite conference, Microsoft employee Jerry Nixon stated that Windows 10 would be the "last version of Windows", a statement that Microsoft confirmed was "reflective" of its view.[14][15] The operating system was considered to be a service, with new builds and updates to be released over time.[16]

In October 2019, Microsoft announced "Windows 10X", a future edition of Windows 10 designed exclusively for dual-touchscreen devices such as the then-upcoming Surface Neo. It featured a modified user interface designed around context-sensitive "postures" for different screen configurations and usage scenarios, and changes such as a centered taskbar and updated Start menu without Windows 10's "live tiles". Legacy Windows applications would also be required to run in "containers" to ensure performance and power optimization. Microsoft stated that it planned to release Windows 10X devices by the end of 2020.[17][18][19]

In May 2020, amid the COVID-19 pandemic, chief product officer for Microsoft Windows and OfficePanos Panay stated that "as we continue to put customers' needs at the forefront, we need to focus on meeting customers where they are now", and therefore announced that Windows 10X would only launch on single-screen devices at first, and that Microsoft would "continue to look for the right moment, in conjunction with our OEM partners, to bring dual-screen devices to market".[20][21]

In January 2021, it was reported that a job listing referring to a "sweeping visual rejuvenation of Windows" had been posted by Microsoft.[22] A visual refresh for Windows, developed under the codename "Sun Valley", was reportedly set to re-design the system's user interface.[23] Microsoft began to implement and announce some of these visual changes and other new features on Windows 10 Insider Preview builds, such as new system icons (which also included the replacement of shell resources dating back as far as Windows 95),[24] improvements to Task View to allow changing the wallpaper on each virtual desktop, emulation of x64 applications on ARM, and adding the Auto HDR feature from Xbox Series X.[25][26]

On May 18, 2021, Head of Windows Servicing and Delivery John Cable stated that Windows 10X had been canceled, and that Microsoft would be "accelerating the integration of key foundational 10X technology into other parts of Windows and products at the company".[27]

Announcement

At the Microsoft Build 2021 developer conference, CEO and chairman Satya Nadella teased about the existence of the next generation of Windows during his keynote speech. According to Nadella, he had been self-hosting it for several months. He also teased that an official announcement would come very soon.[28] Just a week after Nadella's keynote, Microsoft started sending invitations for a dedicated Windows media event at 11 am ET on June 24, 2021.[29][30] Microsoft also posted an 11-minute video of Windows start-up sounds to YouTube on June 10, 2021, with many people speculating both the time of the Microsoft event and the duration of the Windows start-up sound video to be a reference to the name of the operating system as Windows 11.[31][32]

On June 24, 2021, Windows 11 was officially announced at a virtual event hosted by Chief Product OfficerPanos Panay.[33][34][35] According to Nadella, Windows 11 is "a re-imagining of the operating system".[36] Further details for developers such as updates to the Microsoft Store, the new Windows App SDK (code-named "Project Reunion"), new Fluent Design guidelines, and more were discussed during another developer-focused event on the same day.[37][38][39]

Release

The Windows 11 name was accidentally released in an official Microsoft support document in June 2021.[40][41] Leaked images of a purported beta build of Windows 11's desktop surfaced online later on June 15, 2021,[42][43] which were followed by a leak of the aforementioned build on the same day.[44] The screenshots and leaked build show an interface resembling that of the canceled Windows 10X, alongside a redesigned out-of-box experience (OOBE) and Windows 11 branding.[45] Microsoft would later confirm the authenticity of the leaked beta, with Panay stating that it was an "early weird build".[46][47]

At the June 24 media event, Microsoft also announced that Windows 11 would be released in "Holiday 2021", with an exact date not given.[48][49] Its release will be accompanied by a free upgrade for compatible Windows wtfast cracked apk - Free Activators devices through Windows Update.[50] On June 28, Microsoft announced the release of the first preview build and SDK of Windows 11 to Windows Insiders.[51]

On August 31, 2021, Microsoft announced that Windows 11 was to be released on October 5, 2021.[52] The release would be phased, with newer eligible devices to be offered the upgrade first.[6] Since its predecessor Windows 10 was released on July 29, 2015, more than six years earlier, this is the longest time span between successive releases of Microsoft Windows operating systems, beating the time between Windows XP (released on October 25, 2001) and Windows Vista (released on January 30, 2007).[53]

Microsoft officially released Windows 11 on October 4, 2021, at 2:00 p.m. PT, which was October 5 in parts of the world.[54] It can be obtained as an in-place upgrade via either the Windows 11 Installation Assistant application (the successor to the Media Creation Tool from Windows 10, which can also generate an ISO image or USB install media), or via Windows Update on eligible devices.[55]

Updates through Windows Update are a phased rollout, and are distributed on an opt-in basis: Microsoft stated that they "expect all eligible Windows 10 devices to be offered the upgrade to Windows 11 by mid-2022."[56][57] Eligible devices also may present an option to download Windows 11 during the Windows 10 out-of-box experience (OOBE) on a new installation.[58]

Features

Main article: Features new to Windows 11

See also: List of features removed in Windows 11

Windows 11, the first major Windows release since 2015, builds upon its predecessor by revamping the user interface to follow Microsoft's new Fluent Design guidelines. The redesign, which focuses on ease of use and flexibility,[50] comes alongside new productivity and social features and updates to security and accessibility, addressing some of the deficiencies of Windows 10.[59]

The Microsoft Store, which serves as a unified storefront for apps and other content, is also redesigned in Windows 11. Microsoft now allows developers to distribute Win32, progressive web applications, and other packaging technologies in the Microsoft Store, alongside Universal Windows Platform apps.[60] Microsoft also announced plans to allow third-party application stores (such as Epic Games Store) to distribute their clients on Microsoft Store.[61] Windows 11 supports x86-64 software emulation on ARM-based platforms.[62]

The collaboration platform Microsoft Teams is integrated into the Windows 11 user interface, and is accessible via the taskbar. Skype will no longer be bundled with the OS by default.[63][64][65]

Microsoft claims performance improvements such as smaller update sizes, faster web browsing in "any browser", faster wake time from sleep mode, and faster Windows Hello authentication.[63][66]

Windows 11 ships with the Chromium-based Microsoft Edgeweb browser, and does not include or support Internet Explorer.[67] Its rendering engine Trident is still included with the operating system for backwards compatibility reasons, and Edge can be configured with Group Policy to render whitelisted websites in "IE Mode" (which still uses IE's rendering engine Trident, instead of Blink layout engine).[68] Windows 11 is the first version of Windows since the original retail release of Windows 95 to not ship with (the full version of) Internet Explorer.[69]

The updated Xbox app,[70][71] along with the Auto HDR and DirectStorage technologies introduced by the Xbox Series X and Series S, will be integrated into Windows 11; the latter requiring a graphics card supporting DirectX 12 and an NVMesolid-state drive.[71][72]

User interface

A redesigned interface is present throughout the operating system, building upon Fluent Design System; translucency, shadows, a new color palette, and rounded geometry are prevalent throughout the UI. A prevalent aspect of the design is an appearance known as "Mica", described as an "opaque, dynamic material that incorporates theme and desktop wallpaper to paint the background of long-lived windows such as apps and settings".[73][74] Much of the interface and start menu take heavy inspiration from the now-canceled Windows 10X. The Segoe UIfont used since Windows Vista has been updated to a variable version, improving its ability to scale between display resolutions.[76]

The taskbar's buttons are center-aligned by default, and it is permanently pinned to the bottom edge of the screen; it cannot be moved to the top, left, or right edges of the screen as in previous versions of Windows.[77] The notifications sidebar is now accessed by clicking the date and time, with other Quick Actions toggles, as well as volume, brightness, and media playback controls, moved to a new settings pop-up displayed by clicking on the system tray. The "Widgets" button on the taskbar displays a panel with Microsoft Start,[78] a news aggregator with personalized stories and content (expanding upon the "news and interests" panel introduced in later builds of Windows 10).[66][73]Microsoft Teams is similarly integrated with the taskbar, with a pop-up showing a list of recent conversations.[65]

The Start menu has been significantly redesigned, replacing the "live tiles" used by Windows 8.x and 10 with a grid of "pinned" applications, and a list of recent applications and documents.[63][66]File Explorer was updated to replace its ribbon toolbar with a more traditional toolbar, while its context menus have been redesigned to move common tasks (such as copy and paste) to a toolbar along the top of the menu, and hide advanced operations under an overflow menu.[73]

Task View, a feature introduced in Windows 10, features a refreshed design, and supports giving separate wallpapers to each virtual desktop. The window snapping functionality has been enhanced with two additional features; hovering over a window's maximize button displays pre-determined "Snap Layouts" for tiling multiple windows onto a display, and tiled arrangement of windows can be minimized and restored from the taskbar as a "snap group".[66][79] When a display is disconnected in a multi-monitor configuration, the windows that were previously on that display will be minimized rather than automatically moved to the main display. If the same display is reconnected, the windows are restored to their prior location.[80]

Windows Subsystem for Android

Further information: 2021 - Free Activators Astoria and Windows Subsystem for Linux

On October 21, 2021, Windows Subsystem for Android (WSA) became available to Beta channel builds of Windows 11 for users in the United States,[81] which allows users to install and run Android apps. Users can install Android apps through any source using the Android application package (APK) file format.[82] An Amazon Appstore client for Microsoft Store will also be available.[83][84][85][86]

WSA is based on the Intel Bridge runtime compiler; Intel stated that the technology is not dependent on its own CPUs, and will also be supported on x86-64 and ARM CPUs from other vendors.[86]

System security

As part of the minimum system requirements, Windows 11 only runs on devices with a Trusted Platform Module 2.0 security coprocessor.[87][88] According to Microsoft, the TPM 2.0 coprocessor is a "critical building block" for protection against firmware and hardware attacks. In addition, Microsoft now requires devices with Windows 11 to include virtualization-based security (VBS), hypervisor-protected code integrity (HVCI), and Secure Boot built-in and enabled by default.[89] The operating system also features hardware-enforced stack protection for supported Intel and AMD processors for protection against zero-day exploits.

Like its predecessor, Windows 11 also supports multi-factor authentication and biometric authentication through Windows Hello.[89]

Versions

Main article: Windows 11 version history

Windows 11 is available in two main editions; the Home edition is intended for consumer users, while the Pro edition contains additional networking and security features (such as BitLocker), as well as the ability to join a domain.[90] Windows 11 Home may be restricted by default to verified software obtained from Microsoft Store ("S Mode").[91] Windows 11 Home requires an internet connection and Microsoft account in order to complete first-time setup.[92]

Windows 11 SE was announced on November 9, 2021, as an edition exclusively for low-end devices sold in the education market, and a successor to Windows 10 S. It is designed to be managed via Microsoft Intune, and has changes based on feedback from educators to simplify the user interface and reduce "distractions", such as Snap Layouts not containing layouts for more than two applications at once, all applications opening maximized by default, Widgets being removed, and Microsoft Edge being configured by default to allow extensions from Chrome Web Store (primarily to target those migrating from Chrome OS). It is bundled with applications such as Microsoft Office for Microsoft 365, Minecraft Education Edition, and Flipgrid, while OneDrive is used to save files by default. Windows 11 SE does adobe acrobat pro download include Microsoft Store; third-party software is provisioned or installed by administrators.[93][94]

The Windows Insider program carries over from Windows 10, with pre-release builds divided into "Dev" (unstable builds used to test features for future feature updates), "Beta" (test builds for the next feature update; relatively stable in comparison to Dev channel), and "Release Preview" (pre-release builds for final testing of upcoming feature updates) channels.[95]

System requirements

The basic system requirements of Windows 11 differ significantly from Windows 10. Windows 11 only supports 64-bit systems such as those using an x86-64 or ARM64 processor; IA-32 processors are no longer MAGIX Photostory 2022 Deluxe 21.0.1.74 Crack + Serial Key Free Thus, Windows 11 is the first consumer version of Windows not to support 32-bit processors and 16-bit software (though Windows Server 2008 R2 was the first version of Windows NT to not support them).[98][99] The minimum RAM and storage requirements were also increased; Windows 11 now requires at least 4GB of RAM and 64GB of storage. S mode is only supported for the Home edition of Windows 11.[100] As of August 2021, the officially supported list of processors includes Intel Core 8th generation and later, AMD Zen+ and later (which include the "AF" revisions of Ryzen 1000 CPUs, which are underclocked versions of Zen+-based Ryzen 2000 parts that supplant Ryzen 1000 parts that could no longer be manufactured due to a change in process),[101] and Qualcomm Snapdragon 850 and later.[102] The compatibility list includes the Intel Core i7-7820HQ, a seventh-generation processor used by the Surface Studio 2,[103] although only on devices that shipped with DCH-based drivers.[104]

Legacy BIOS is no longer supported; a UEFI system with Secure Boot and a Trusted Platform Module (TPM) 2.0 security coprocessor is now required.[77][105][106][107] The TPM requirement in particular has led to confusion as many motherboards do not have TPM support, or require a compatible TPM to be physically installed onto the motherboard. Many newer CPUs also include a TPM implemented at the CPU level (with AMD referring to this "fTPM", and Intel referring to it as "Platform Trust Technology" [PTT]),[108] which might be disabled by default and require changing settings in the computer's UEFI firmware,[109] or an UEFI firmware update that is configured to automatically enable the firmware TPM upon installation.[110]

Original equipment manufacturers can still ship computers without a TPM 2.0 coprocessor upon Microsoft's approval.[111][112] Devices with unsupported processors are not blocked from installing or running Windows 11; however, a clean install or upgrade using ISO installation media must be performed as Windows Update will not offer an upgrade from Windows 10.[113] Additionally, users must also accept an on-screen disclaimer stating that they will not be entitled to receive updates, and that damage caused by using Windows 11 on an unsupported configuration are not covered by the manufacturer's warranty.[114][115] Some third-party software may refuse to run on unsupported configurations of Windows 11.[116]

Reception

Pre-release

Reception of Windows 11 upon its reveal was positive, with critics praising the new design and productivity features.[117] However, Microsoft was criticized for creating confusion over the minimum system requirements for Windows 11.[118] The increased system requirements (compared to those of Windows 10) initially published by Microsoft could see as many as 60 percent of existing Windows 10 PCs unable to upgrade to Windows 11,[119] which has faced concerns that this will make the devices electronic waste.[120]

It has been theorized that these system requirements were a measure intended to encourage the purchase of new PCs, especially amid a downturn in PC sales and increased prices due to the global chip shortage.[73] While Microsoft has not specifically acknowledged this when discussing the cutoff, it was also acknowledged that the sixth and seventh generation of Intel Core processors were prominently afflicted by CPU-level security vulnerabilities such as Meltdown and Spectre, and that newer CPUs manufactured since then had increased mitigations against the flaws.[73][121] Research Vice President of Gartner Stephen Kleynhans felt that Microsoft was "looking at the entire stack from the hardware up through the applications and the user Security - Crack Key For U and trying to make the entire stack work better and more securely.[121]

Launch

Andrew Cunningham of Ars Technica praised the improvements to its visual design (describing the new "Mica" appearance as reminiscent of the visual appearance of iOS and macOS, and arguing that Microsoft had "[made] a serious effort" at making the user-facing aspects of Windows 11 more consistent visually), window management, performance (assessed as being equivalent to if not better than Windows 10), other "beneficial tweaks", and its system requirements having brought greater public attention to hardware security features present on modern PCs. Criticism was raised towards Widgets' lack of support for third-party content (thus limiting it to Microsoft services only), regressions in taskbar functionality and customization, the inability to easily select default applications for common corel aftershot pro 3 crack download - Crack Key For U such as web browsing (now requiring the user to select the browser application for each file type individually), and Microsoft's unclear justification for its processor compatibility criteria. Cunningham concluded that "as I've dug into [Windows 11] and learned its ins and outs for this review, I've warmed to it more", but argued that the OS was facing similar "public perception" issues to Windows Vista and Windows 8. However, he noted that 11 did not have as many performance issues or bugs as Vista had upon its release, nor was as "disjointed" as 8, and recommended that users who were unsure about the upgrade should stay on Windows 10 in anticipation of future updates to 11.[73]

Tom Warren of The Verge described Windows 11 as being akin to a house in the middle of renovations, but that "actually using Windows 11 for the past few months hasn't felt as controversial as I had expected"—praising its updated user interface as being more modern and reminiscent of iOS and Chrome OS, the new start menu for feeling less cluttered than the Windows 10 iteration, updates to some of its stock applications, and Snap Assist. Warren noted that he rarely used the Widgets panel or Microsoft Teams, citing that he preferred the weather display that later versions of Windows 10 offered, and didn't use Teams to communicate with his friends and family. He also acknowledged the expansion fonepaw support - Free Activators Microsoft Store to include more "traditional" desktop applications. However, he felt that Windows 11 still felt like a work in progress, noting UI inconsistencies (such as dark mode and new context menu designs not being uniform across all dialogues and applications, and the modern Settings app still falling back upon legacy Control Panel applets for certain settings), regressions to the taskbar (including the inability to move it, drag files onto taskbar buttons in order to focus the corresponding application, and the clock only shown on the primary display in multi-monitor configurations), and promised features (such as dynamic refresh rate support and a universal microphone mute button) not being present on the initial release. Overall, he concluded that "I wouldn't rush out to upgrade to Windows 11, but Folder lock software freeware download - Activators Patch also wouldn't avoid it. After all, Windows 11 still feels familiar and underneath all the UI changes, it's the same Windows we've had for decades."[122]

PC World was more critical, arguing that Windows 11 "sacrifices productivity for personality, but without cohesion", commenting upon changes such as the inability to use local "offline" accounts on Windows 11 Home, regressions to the taskbar, a "functionally worse" start menu, Microsoft Teams integration having privacy implications and being a ploy to coerce users into switching to the service, File Explorer obscuring common functions under unclear icons, using "terribly sleazy" behaviors to discourage changing the default web browser from Microsoft Edge, and that the OS "anecdotally feels less responsive, slower, and heavier than Windows 10." It was concluded that Windows 11 "feels practical and productive, but less so than its predecessor in many aspects", while its best features were either "hidden deeper within", required specific hardware (DirectStorage, Auto HDR) or were not available on launch (Android app support).[123]

See also

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  89. ^"Compare Windows 11 Home vs Pro Versions June 12, 2021 - Free Activators

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1 Replies to “June 12, 2021 - Free Activators”

  1. I did not even expect pro apps in the new version of ipad os.I would have been ok with a better file system or more apps running at once while multitasking,but instead apple took a big shit on us and failed to deliver.This event was a big disappointment.Almost the entire IOS part was about facetime and everything about homekit was already expected to come.

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